Search results

This paper aims to inspect the effect of indirect elevated temperature on the mechanical performance of nano silica concrete (NSC). The effect on both compressive and bond strengths is studied. Pre- and post-exposure to elevated temperature ranges of 200 to 600°C is examined. A range covered by three percentages of 1.5, 3 and 4.5 per cent nano silica (NS) in concrete mixes is tested.

Pre-exposure mechanical tests (normal conditions – room temperature), using 3 per cent NS in the concrete mix, led to the highest increase in both compressive and bond strengths (43 per cent and 38.5 per cent, respectively), compared to the control mix without NS (based on 28-day results). It is worth noticing that adding NS to the concrete mixes does not have a significant effect on improving early-age strength. Besides, permeability tests are performed on NSC with different NS ratios. NS improved the concrete permeability for all tested percentages of NS. The maximum reduction is accompanied by the maximum percentage used (4.5 per cent NS in the NSC mix), reducing permeability to half the value of the concrete mix without NS. As for post-exposure to elevated-temperature mechanical tests, NSC with 1.5 per cent NS exhibited the lowest loss in strength owing to indirect heat exposure of 600°C; the residual compressive and bond strengths are 73 per cent and 35 per cent, respectively.

The dispersion technique of NS has a key role in NSC-distinguished mechanical performance with NSC having lower NS percentages. NS significantly improved bond strength. NS has a remarkable effect on elevated temperature endurance. The bond strength of NSC exposed to elevated temperatures suffered faster deterioration than compressive strength of the exposed NSC.

A special scale factor needs to be investigated for the NSC.

Although a lot of effort is placed in evaluating the benefits of using nano materials in structural concrete, this paper presents one of the first outcomes of the thermal effects on concrete mixes with NS as a partial cement replacement.

Nano-Clay (NC) is reported as a candidate partial replacement for cement, due to its abundance and relatively low cost - beside reported promotion of different concrete properties. On the other hand, Steel Fibres (SF) has proven to have a positive effect on post fire exposure residual strength of concrete. This paper aims to present the outcomes of a comprehensive research program assessing a hybrid mix between NC and SF in concrete mixtures (NCSF-CRETE).

Physical chemical and physical characterization of NC is performed using different tools as XRF spectrometer, and TEM micrograph. Fresh concrete properties of NSCF-CRETE as slump and air content are investigated. Enhancement in permeability using NSCF is verified by comparing its resistance to the penetration of chlorides resistance with regular concrete mix. Besides, the proposed NCSF-CRETE compressive strength is evaluated compared to mixes with NC and SF each used separately at different curing ages. Besides, NSCF and compared mixes are exposed to an indirect fire testing program – two hours exposure – for: 300, 450 and 600°C. Degradation in compressive strength was investigated after exposure to different temperatures and percentage of residual strength is reported.

Results indicated an improved performance of NCSF -CRETE of about 40% compared to regular concrete in compressive strength at normal conditions. This improvement extended to its behavior when subjected to indirect fire exposure NSCF also maintained 40% more strength than the residual in regular concrete mix – which suffered severe damage – after 2 h exposure to 600°C.

Using NCSF-Crete allows retrofitting the structure after exposure to such drastic conditions.

This paper presents the second part of the investigation on resistance to elevated temperatures of a proposed hybrid composite concrete (NCSF-Crete) mix. The composite including nano metakaolin (NC) and steel fibers (SF) in addition to regular concrete components has proven -in the first published part-earlier promoted fresh concrete behavior, and to have reduced loss in compressive strength after exposure to a wide range of elevated temperatures. This presented work evaluates another two critical mechanical characteristics for the proposed composite -namely- splitting and bond strengths.

A modified formula correlating splitting and compressive strength (28 days) based on experiments results for NCSF is proposed and compared to formulas derived for regular concrete in different design codes. Finally, both spitting and bond strengths are evaluated pre- and post-exposure to elevated temperatures reaching 600 °C for two hours.

The proposed NCSF-Crete shows remarkable fire endurance, especially in promoting bond strength as after 600 °C heat exposure tests, it maintained strength equivalent to 70% of a regular concrete control mix at room temperature. Improving residual splitting strength was very significant up to 450 °C exposure.

Obvious deterioration is monitored in splitting resistance for all concretes at 600 °C.

This proposed composite improved elevated heats resistance of the most significant concrete mechanical properties.

Using a more green and sustainable constituents in the composite.

The proposed composite gathers the merits of using NC and SF, each has been investigated separately as an addition to concrete mixes.

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated.

The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins.

The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms.

Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.