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Article
Publication date: 10 September 2024

Shi Xu, Hongyu Gao, Fukang Yang, Ziyue Zhang, Shuolei Wang, Xiaojian Jiang and Yubing Dong

The purpose of this study is to improve the mechanical properties, thermal insulation properties and flame retardant properties of polyethylene terephthalate (PET), the organic…

Abstract

Purpose

The purpose of this study is to improve the mechanical properties, thermal insulation properties and flame retardant properties of polyethylene terephthalate (PET), the organic montmorillonite (OMMT)/SiO2 aerogel/PET composites and fibers were prepared, and the effects of the OMMT/SiO2 aerogel on the structure, thermal conductivity and flame retardance of the OMMT/SiO2 aerogel/PET composites and their fibers were systematically investigated.

Design/methodology/approach

The OMMT/SiO2 aerogel/PET composites and fibers were prepared by in-situ polymerization and melt spinning using SiO2 aerogel as thermal insulation filler and OMMT (DK2) as comodified filler.

Findings

The experimental results showed that OMMT improved the crystallization properties of PET. Compared with the crystallinity of SiO2 aerogel/PET composites (34.8%), SiO2 aerogel/PET composites and their fibers reached 45.1% and 49.2%, respectively. The breaking strength of the OMMT/SiO2 aerogel/PET composite fibers were gradually increased with the OMMT content. When the content of OMMT was 0.8 wt.%, the fracture strength of the composite fibers reached 4.40 cN/dtex, which was 54% higher than that of the SiO2 aerogel/PET fiber. In addition, the thermal insulation properties of the composites and their fibers were improved by addition of fillers, and at the same time reached the flame retardant level. The thermal conductivity of the 0.8 wt.% OMMT/SiO2 aerogel/PET composites was 101.78 mW/(m·K), which was 49.3% and 58.8% lower than that of the SiO2 aerogel/PET composites and the pure PET, respectively. The thermal conductivity of the fiber fabrics woven from the 0.8 wt.% OMMT/SiO2 aerogel/PET composites was 28.18 mW/(m·K), which was 29.0% and 44.6% lower than that of the SiO2 aerogel/PET composite fiber fabrics and PET fiber fabrics. The flame retardancy of the composites was improved, with an limiting oxygen index value of 29.2% for the 0.8 wt.% OMMT/SiO2 aerogel/PET composites, which was 4.1% higher compared to the SiO2 aerogel/PET composites, and achieved the flame retardant level.

Research limitations/implications

The SiO2 aerogel/PET composites and their fibers have good mechanical properties, flame retardant properties and thermal insulation properties, exhibited good potential for application in the field of thermal insulation, such as warm clothing. Nowadays, as the energy crisis is becoming more and more serious, it is very important to improve the thermal insulation properties of PET to reduce energy losses and mitigate the energy crisis.

Originality/value

In this study, PET based composites and their fibers with excellent mechanical properties, thermal insulation properties and flame retardant property were obtained by using three-dimensional network porous silica aerogel with low density and low thermal conductivity as the thermal insulation functional filler and two-dimensional layered OMMT as the synergetic modified filler.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 April 2024

Fukang Yang, Wenjun Wang, Yongjie Yan and YuBing Dong

Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to…

Abstract

Purpose

Polyethylene terephthalate (PET) as a fiber molding polymer is widely used in aerospace, electrical and electronic, clothing and other fields. The purpose of this study is to improve the thermal insulation performance of polyethylene terephthalate (PET), the SiO2 aerogel/PET composites slices and fibers were prepared, and the effects of the SiO2 aerogel on the morphology, structure, crystallization property and thermal conductivity of the SiO2 aerogel/PET composites slices and their fibers were systematically investigated.

Design/methodology/approach

The mass ratio of purified terephthalic acid and ethylene glycol was selected as 1:1.5, which was premixed with Sb2O3 and the corresponding mass of SiO2 aerogel, and SiO2 aerogel/PET composites were prepared by direct esterification and in-situ polymerization. The SiO2 aerogel/PET composite fibers were prepared by melt-spinning method.

Findings

The results showed that the SiO2 aerogel was uniformly dispersed in the PET matrix. The thermal insulation coefficient of PET was significantly reduced by the addition of SiO2 aerogel, and the thermal conductivity of the 1.0 Wt.% SiO2 aerogel/PET composites was reduced by 75.74 mW/(m · K) compared to the pure PET. The thermal conductivity of the 0.8 Wt.% SiO2 aerogel/PET composite fiber was reduced by 46.06% compared to the pure PET fiber. The crystallinity and flame-retardant coefficient of the SiO2 aerogel/PET composite fibers showed an increasing trend with the addition of SiO2 aerogel.

Research limitations/implications

The SiO2 aerogel/PET composite slices and their fibers have good thermal insulation properties and exhibit good potential for application in the field of thermal insulation, such as warm clothes. In today’s society where the energy crisis is becoming increasingly serious, improving the thermal insulation performance of PET to reduce energy loss will be of great significance to alleviate the energy crisis.

Originality/value

In this study, SiO2 aerogel/PET composite slices and their fibers were prepared by an in situ polymerization process, which solved the problem of difficult dispersion of nanoparticles in the matrix and the thermal conductivity of PET significantly reduced.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 21 October 2024

Hongyu Gao, Shi Xu, Fukang Yang, Ziyue Zhang, Shuolei Wang, Xiaojian Jiang and Yubing Dong

Crystallization kinetics is a key factor that controls the crystallization process of polymers and influences the crystallinity and morphology of polymers. This study aims to…

Abstract

Purpose

Crystallization kinetics is a key factor that controls the crystallization process of polymers and influences the crystallinity and morphology of polymers. This study aims to explore the effects of functional filler SiO2 aerogel and co-modified filler organic montmorillonite (OMMT) on the crystallization process of polyester polyethylene terephthalate (PET). In this study, the nonisothermal crystallization kinetics of OMMT/SiO2 aerogel/PET composites were studied by Jeziorny method.

Design/methodology/approach

The catalyst (Sb2O3), OMMT and SiO2 aerogel were uniformly dispersed in ethylene glycol (EG). Then, the mixture and terephthalic acid (PTA) were put into a semicontinuous polyester synthesis reactor, and the SiO2 aerogel/PET composites were prepared by esterification and polycondensation.

Findings

Non-isothermal kinetic results showed that the high cooling rate hindered the movement of the molecular chain of the composites and made the crystallization peak move toward the low-temperature direction. With the increase of crystallization temperature (Tc), the melt crystallization rate decreases, but the cold crystallization rate increases. The introduction of OMMT and SiO2 aerogel condensation affected the nucleation and growth mode of crystals, lengthened the time with a relative crystallinity of 50% (t1/2) and decreased the crystallization rate. OMMT improved the crystallinity and Avrami index of the composites.

Research limitations/implications

Effects of thermal insulation functional filler SiO2 aerogel and co-modified filler OMMT on the crystallization process of PET were studied by non-isothermal crystallization kinetics, and the effects of SiO2 aerogel and OMMT on the nucleation mechanism of PET were clarified, which provided a theoretical reference for the preparation and performance optimization of PET matrix composites.

Originality/value

In this study, the OMMT/SiO2 aerogel/PET composites were prepared by in-situ polymerization, the crystallinity of PET matrix composites was improved, and the effects of OMMT and SiO2 aerogel on the crystallization process of PET were clarified.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 August 2016

Fuchuan Huang, Fukang Deng, Kang-Chun Li and Ke Qin

Aiming at the high temperature, high speed, high precision and high surface quality of the copper belt cold rolling, the purpose of this paper is to develop a new type of…

Abstract

Purpose

Aiming at the high temperature, high speed, high precision and high surface quality of the copper belt cold rolling, the purpose of this paper is to develop a new type of lubricant for cold rolled copper belt.

Design/methodology/approach

The component of the developed oil was determined based on the physical and chemical properties of the base oil and the tribological properties, the oxidation resistance properties, the rust resistance properties, the anti-foam properties, the demulsibility and the other properties of the additives. The orthogonal experiment method was used to determine the optimum adding amount of the additives; finally, the developed oil formulation was determined.

Findings

The physical and chemical experiment results show that the developed oil has a good performance of oil film bearing capacity and oxidation resistance. The simulation of rolling experiment found that the developed oil can significantly reduce rolling pressure and effectively reduce the friction in the process of rolling.

Originality/value

The experimental results show that the developed oil has excellent performance and can meet the requirement of lubrication in the process of cold rolling copper belt.

Details

Industrial Lubrication and Tribology, vol. 68 no. 5
Type: Research Article
ISSN: 0036-8792

Keywords

Content available
Article
Publication date: 1 March 2017

Grace Chun Guo, Crystal X. Jiang and Qin Yang

In recent decades many emerging markets (EMFs) have undertaken entrepreneurial transformations to adapt to institutional transition and industrial change. Corporate…

2825

Abstract

In recent decades many emerging markets (EMFs) have undertaken entrepreneurial transformations to adapt to institutional transition and industrial change. Corporate entrepreneurship (CE) provided EMFs viable ways to revitalize, reconfigure, and transform successfully with the dynamic environment. Although previous research examined government roles on EMFs' CE activities, little is known about the mechanisms of how government exerts influence on CE activities. To fully understand CE of EMFs, we propose a stage model to explore specific roles governments play that affect CE activities over time. In particular, we investigate how governments' grabbing hand, helping hand, and invisible hand roles affected Chinese auto firms' CE activities at different stages from 1980 to 2016. Government involvement is summarized and the advantages and disadvantages of these roles are analyzed.

Details

New England Journal of Entrepreneurship, vol. 20 no. 1
Type: Research Article
ISSN: 2574-8904

Open Access
Article
Publication date: 22 December 2020

Jie Meng and Fenghua Wu

As a crucial institutional form established since the Chinese economic reform, the system of competitive local governments has been shaping the characteristics of China's…

1185

Abstract

Purpose

As a crucial institutional form established since the Chinese economic reform, the system of competitive local governments has been shaping the characteristics of China's socialist market economy to a considerable degree.

Design/methodology/approach

This study not only adopts the view of existing studies that attribute the economic motive of local governments to rent and consider land public finance as a means through which local governments carry out strategic investment but also attempts to further develop the view within a Marxist analytical framework.

Findings

As a result, the local governments have helped to maintain an incredibly high investment rate over a considerable period of time, facilitating the continuous, rapid growth of the Chinese economy.

Originality/value

This study concludes that China's local governments function as the productive allocator and user of rent in the strategic investment based on land public finance and thereby embed themselves in the relative surplus-value production initially arising from competition amongst enterprises, forming the dual structure of relative surplus-value production unique to China's economy.

Details

China Political Economy, vol. 3 no. 2
Type: Research Article
ISSN: 2516-1652

Keywords

Article
Publication date: 5 July 2013

Qiang Ding and Michèle E.M. Akoorie

– The purpose of this paper is to analyze the historical development and characteristics of the globalizing Chinese automobile industry.

3707

Abstract

Purpose

The purpose of this paper is to analyze the historical development and characteristics of the globalizing Chinese automobile industry.

Design/methodology/approach

This study is positioned as an exploratory case study, using data triangulation techniques based on archival research and published reports of statistical agencies both at central government and single industry level.

Findings

China's automobile industry represents an extraordinary case of a development path toward globalization in a transitional economy. One of the obvious characteristics of the auto industry is that it necessitates technology transfer and innovative learning, which can be regarded as an important aspect of maintaining competitiveness in industrialization and global competition. The automobile industry in China is also characterized by state intervention and industrial regulations. The state initiated open-door reform has led to a mixed regulatory mechanism including both market-based competition and the legacy of a command economy. Other major features are demonstrated as follows: state-owned auto enterprises have been gradually given more freedom in the decision-making processes; the Chinese auto industry has shown phenomenal growth in the country's economic development with an average annual rate of about 9 percent. This achievement combined with the increasing impacts of globalization of production and market expansion has undoubtedly led to the increasing inflows of foreign direct investment in the form of international partnerships between the auto-producing MNCs and major local Chinese firms as per the industrial policies in the Chinese automobile industry.

Originality/value

This paper addresses an important topic, the historical development path of the Chinese automobile industry, but to date, it has received very little research attention. It advances the institution-based perspective and therefore develops a better understanding of changes in China's automobile industry over the past decades since 1949 and concludes that the combination of the influences of foreign technology, China's industrial policies and institutional dynamic processes has resulted in a unique dynamic development path for the globalizing Chinese automobile industry.

Details

Journal of Technology Management in China, vol. 8 no. 2
Type: Research Article
ISSN: 1746-8779

Keywords

Article
Publication date: 24 December 2020

Xuesong Cao, Xican Li, Wenjing Ren, Yanan Wu and Jieya Liu

This study aims to improve the accuracy of hyperspectral estimation of soil organic matter content.

Abstract

Purpose

This study aims to improve the accuracy of hyperspectral estimation of soil organic matter content.

Design/methodology/approach

Based on the uncertainty in spectral estimation, 76 soil samples collected in Zhangqiu District, Jinan City, Shandong Province, were studied in this paper. First, the spectral transformation of the spectral data after denoising was carried out by means of 11 transformation methods such as reciprocal and square, and the estimation factor was selected according to the principle of maximum correlation. Secondly, the grey weighted distance was used to calculate the grey relational degree between the samples to be estimated and the known patterns, and the local linear regression estimation model of soil organic matter content was established by using the pattern samples closest to the samples to be identified. Thirdly, the models were optimized by gradually increasing the number of modeling samples and adjusting the decision coefficient, and a comprehensive index was constructed to determine the optimal predicted value. Finally, the determination coefficient and average relative error are used to evaluate the validity of the model.

Findings

The results show that the maximum correlation coefficient of the seven estimated factors selected is 0.82; the estimation results of 14 test samples are of high accuracy, among which the determination coefficient R2 = 0.924, and the average relative error is 6.608%.

Practical implications

Studies have shown that it is feasible and effective to estimate the content of soil organic matter by using grey correlation local linear regression model.

Originality/value

The paper succeeds in realizing both the soil organic matter hyperspectral grey relation estimating pattern based on the grey relational theory and the estimating pattern by using the local linear regression.

Details

Grey Systems: Theory and Application, vol. 11 no. 4
Type: Research Article
ISSN: 2043-9377

Keywords

Article
Publication date: 16 June 2023

Fan Chao, Xin Wang and Guang Yu

Sharing and disseminating debunking information are critical to correcting rumours and controlling disease when dealing with public health crises. This study investigates the…

Abstract

Purpose

Sharing and disseminating debunking information are critical to correcting rumours and controlling disease when dealing with public health crises. This study investigates the factors that influence social media users' debunking information sharing behaviour from the perspective of persuasion. The authors examined the effects of argument adequacy, emotional polarity, and debunker's identity on debunking information sharing behaviour and investigated the moderating effects of rumour content and target.

Design/methodology/approach

The model was tested using 150 COVID-19-related rumours and 2,349 original debunking posts on Sina Weibo.

Findings

First, debunking information that contains adequate arguments is more likely to be reposted only when the uncertainty of the rumour content is high. Second, using neutral sentiment as a reference, debunking information containing negative sentiment is shared more often regardless of whether the government is the rumour target, and information containing positive sentiment is more likely to be shared only when the rumour target is the government. Finally, debunking information published by government-type accounts is reposted more often and is enhanced when the rumour target is the government.

Originality/value

The study provides a systematic framework for analysing the behaviour of sharing debunking information among social media users. Specifically, it expands the understanding of the factors that influence debunking information sharing behaviour by examining the effects of persuasive cues on debunking information sharing behaviour and the heterogeneity of these effects across various rumour contexts.

Details

Internet Research, vol. 34 no. 5
Type: Research Article
ISSN: 1066-2243

Keywords

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