Youssef L. Nashed, Fouad Zahran, Mohamed Adel Youssef, Manal G. Mohamed and Azza M. Mazrouaa
The purpose of this study is to examine how well reinforced concrete structures can be shielded against concrete carbonation using anti-carbonation coatings based on synthetic…
Abstract
Purpose
The purpose of this study is to examine how well reinforced concrete structures can be shielded against concrete carbonation using anti-carbonation coatings based on synthetic polymer.
Design/methodology/approach
Applying free radical polymerization, an acrylate terpolymer emulsion that a surfactant had stabilized was created. A thermogravimetric analysis, minimum film-forming temperature, Fourier transform infrared spectroscopy and particle size distribution are used to characterize the prepared eco-friendly water base acrylate terpolymer emulsion. Using three different percentages of the acrylate terpolymer emulsion produced, 35%, 45% and 55%, the anti-carbonation coating was formed. Tensile strength, tensile strain, elongation, crack-bridging ability, carbon dioxide permeability, chloride ion diffusion, average pull-off adhesion strength, water vapor transmission, gloss, wet scrub resistance, QUV/weathering and storage stability are the characteristics of the anti-carbonation coating.
Findings
The formulated acrylate terpolymer emulsion enhances anti-carbonation coating performance in CO2 permeability, Cl-diffusion, crack bridging, pull-off adhesion strength and water vapor transmission. The formed coating based on the formulated acrylate terpolymer emulsion performed better than its commercial counterpart.
Practical implications
To protect the steel embedded in concrete from corrosion and increase the life span of concrete, the surface of cement is treated with an anti-carbonation coating based on synthetic acrylate terpolymer emulsion.
Social implications
In addition to saving lives from building collapse, it maintains the infrastructure for the long run.
Originality/value
The anti-carbonation coating, which is based on the synthetic acrylate terpolymer emulsion, is environmentally benign and stops the entry of carbon dioxide and chlorides, which are the main causes of steel corrosion in concrete.
Details
Keywords
Nader L. Labib, Fouad Zahran, Mohamed Adel Youssef, Azza M. Mazrouaa and Manal Gamal Mohamed
This study aims to extend the pot life without altering the qualities and performance of the coating, which is important to increase when manufacturing polyurethane coatings.
Abstract
Purpose
This study aims to extend the pot life without altering the qualities and performance of the coating, which is important to increase when manufacturing polyurethane coatings.
Design/methodology/approach
An acrylic polyol from a mixture of different monomers of hydroxypropyl methacrylate, methacrylic acid, 2-ethylhexyl acrylate, methyl methacrylate and n-butyl methacrylate was prepared with different ratios of 2,4-pentanedione as a pot life extender. The reaction takes place in presence of di-tert-butyl peroxide as initiator with samples (T1–T7). The physical properties of prepared acrylic polyol were characterized. Then, coating polyurethane varnish was prepared from the prepared acrylic polyol with an aliphatic polyisocyanate in a 1:1 equivalent ratio of OH:NCO at room temperature, in presence of paint thinner (diluents/solvent) and dibutyltin dilaurate as a catalyst to give samples (T1C–T7C). This coating was evaluated via Fourier-transform infrared spectroscopy, drying time, hardness and gloss, distinctness of image and reflected image quality.
Findings
The coating has a prolonged pot life while still maintaining the other qualities, thanks to the greater 2,4-pentanedione content.
Originality/value
It is desired to have a paint which has a satisfactory pot life, short curing time and reduces many drawbacks such as inefficient working and deterioration of the paint before application.
Details
Keywords
Abdel Rehim Sabry and A.E. Jeffreys
The National Library of the Arab Republic of Egypt is preparing a computer‐based catalogue of its acquisitions from 1870 to 1969. Keypunching has begun with the Arabic holdings…
Abstract
The National Library of the Arab Republic of Egypt is preparing a computer‐based catalogue of its acquisitions from 1870 to 1969. Keypunching has begun with the Arabic holdings, and is complete for science and technology classes. The paper discusses the problems of data preparation and computer printout of Arabic text.
This study aims to test the role of the state of occupation, represented in Israel, as one of the most significant challenges, which faces the Jordanian water security. Where…
Abstract
Purpose
This study aims to test the role of the state of occupation, represented in Israel, as one of the most significant challenges, which faces the Jordanian water security. Where Israel expands in its policy and ideology everyday its hydro-hegemony over the Jordanian waters. Hence, its acts result in negative consequences on the Jordanian water and food security, which in turn affects the Jordanian national security as a whole.
Design/methodology/approach
This study relied on the following two approached to tackle its problem: first: descriptive approach: the descriptive approach depends on defining the apparent features and describing their nature and the type of the relationship between its variables. It aims to achieving a better and deeper understanding on the situation of its future policies and measures. And research uses the system analysis approach to handle the subject matter. Given the influence of water on the development, Jordan, as an organic or a political and social state, takes into account the reasons and causes of development. Jordan turns into an active political state, with water as an influencing factor on it. This premise represents the core of the system analysis approach.
Findings
The research concluded that the Israeli theft of the Jordanian waters is the main factor in the Jordanian water crisis. If Jordan had received its usurped water rights by Israel, it could have been able to solve its water issue represented in the increasing deficit in its water balance. Therefore, the Israeli hydro-hegemony on the Jordanian water resources caused the imbalance in its water security and, in turn, caused the development process to falter in general.
Originality/value
The value of the research lies in the fact that it addresses the most important reasons behind the water crisis in Jordan, represented in the Israeli control over the Jordanian water resources and the research shows that the amount of water stolen by Israel is enough to solve the water crisis in Jordan.
Details
Keywords
Laila M. Elattar, Sawsan S. Darwish, Usama M. Rashed, Maha Ahmed Ali and Shaimaa M. Eldeighdye
This paper aims at examining the potentiality of using Hibiscus sabdariffa L. calyces’ (Hs) aqueous extract to remove soot stains from the surface of fire-damaged silver gelatin…
Abstract
Purpose
This paper aims at examining the potentiality of using Hibiscus sabdariffa L. calyces’ (Hs) aqueous extract to remove soot stains from the surface of fire-damaged silver gelatin prints. It further studies the cleaning efficiency and impact of both a contact method and a noncontact method with argon dielectric barrier discharge plasma (DBD Ar. plasma) on the different properties of silver gelatin prints. Accordingly, it prompts using economic, eco-friendly materials and methods in the photograph conservation field.
Design/methodology/approach
To achieve the aims of this paper, four silver gelatin prints were stained with soot and treated with the Hs aqueous extract as a contact method and DBD Ar. plasma combined with the aqueous extract as a noncontact method. The assessment was carried out using digital microscopy, atomic force microscopy and spectrophotometer to study the efficiency of the tested treatments and their impact on the surface of the photographs. Fourier transform infrared was used to monitor the state of the binder after cleaning. Furthermore, the pH and the mechanical properties were measured.
Findings
The contact method resulted in lower concentrations of Hs extract that efficiently cleaned the surface without causing any stains or damage to the treated photographs. The noncontact method (plasma with an aqueous extract) proved to be less effective in cleaning and made the binder more susceptible to deterioration.
Originality/value
This paper reveals the success of Hs aqueous extract in cleaning soot on vulnerable photographs' surfaces.
Details
Keywords
Wael Mohamed Abdelmaksoud, Mohamed Aboaly, Said Teleb, Adel Mohy-Eldin Gabr and Mostafa Abdellah Sayed
The pursuit of manufacturing new inks with low financial cost is an urgent economic demand. Thus, the purpose of this paper is to synthesize some new pigments derived from Lithol…
Abstract
Purpose
The pursuit of manufacturing new inks with low financial cost is an urgent economic demand. Thus, the purpose of this paper is to synthesize some new pigments derived from Lithol Rubine (LR) via a successful simple route and to investigate their physicochemical properties for usage in the inks industry.
Design/methodology/approach
Two novel pigments were generated during the reaction of LR with Mn(II) and Co(II) salts in ethanolic solutions. The obtained pigments were isolated as solid compounds and characterized through elemental analysis, UV–vis, Fourier transform infrared, 1H NMR spectra, oil absorption, specific gravity, melting point, molar conductivity and magnetic moment measurements. Their dyeing and durability characteristics were examined using American Standard Testing Methods. The synthesized pigments were then applied in inks formulation.
Findings
The printing inks containing the two new pigments (LR–Mn and LR–Co) were compared to (GF 59-606 and GF 59-616), respectively. The results of this study showed that the performance of newly prepared pigments was comparable to that of commercial pigments currently in use in the inks industry.
Practical implications
LR and its new derivative pigments can be used in other different applications such as paper coating, crayon, rubber and paint industries.
Originality/value
The authors designed an efficient synthesis for some novel pigments. The synthesis technique is featured by a short reaction time, high yields and ease of use. The pigments developed would be good and cost-effective substitute for the original commercially available and expensive pigments used in the inks industry.