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Motivated by the globally increasing concern over environmental protection, the interest of a large part of the scientific community focuses on the development of green surfactants aiming to replace traditional toxic surfactants-based alternatives. The purpose of this paper is to prepare acrylate copolymer latex modified with fluorine and silicone monomer, which is emulsified with the green surfactants of sodium rosinate and alkyl polyglycoside (APG).

A series of acrylic copolymer latexes containing fluorine–silicon have been prepared by semi-continuous seed emulsion polymerisation of mixed monomers of methyl methacrylate (MMA), butyl acrylate (BA), hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by green mixed surfactants of sodium rosinate and APG.

The optimum recipe of preparing the emulsion is as follows: the amount of emulsifiers is 6 per cent and the mass ratio of sodium rosinate to APG is 1:3. The amount of initiator is 0.4 per cent, and the amounts of the silicon monomer and fluorine monomer are 5 and 7 per cent, respectively. In comparison with the acrylate latex prepared without fluorine monomer and silicon monomer, the thermal stability and the water resistance of the film of the resultant latex clearly improved.

The acrylic copolymer latexes containing fluorine–silicon emulsified with green surfactants can be used in the coatings, adhesives, finishing agents and so on.

The acrylic copolymer latexes containing fluorine–silicon have been prepared by semi-continuous seed emulsion polymerisation. The green mixed surfactants of sodium rosinate and APG have been used as the emulsifiers to replace traditional toxic surfactants-based alternatives.

Presently, a wide range of polyurethane adhesives can be obtained using different kinds of polyols and isocyanates. However, the applied temperature of the polyurethane adhesive is not more than 80°C. The film of polyurethane adhesive will be softened and deformed when its applied temperature is more than 100°C. Thus, the mechanical property of the polyurethane adhesive is decreased clearly, which limits its further application. The purpose of the study is to improve the heat resistance of polyols, especially polyester polyols and its resultant polyurethane adhesives.

The more rigid benzene ring is introduced into the polyester polyols to improve the heat resistance of its resultant polyurethane adhesive.

The more rigid benzene ring has ben introduced into the polyester polyols and the heat resistance of its resultant polyurethane adhesive is improved.

The polyester polyols with more rigid benzene ring have been prepared successfully by the vacuum melting method when diethylene glycol, neopentyl glycol, 1,6-hexanediol, ethanediol, isophthalic acid, terephthalic acid, sebacic acid and adipic acid are used as raw materials and tetra-isopropyl titanate is adopted as the catalyst.