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Book part
Publication date: 10 August 2018

Hans Vermaak and Léon de Caluwé

The colors of change is an overview of change paradigms, created about two decades ago, that has been intensively used, tested, refined, shared, and elaborated by practitioners…

Abstract

The colors of change is an overview of change paradigms, created about two decades ago, that has been intensively used, tested, refined, shared, and elaborated by practitioners and academics alike. Here, the “color theory” is presented as it is now, and is situated within the literature. Its four main applications are described as well as rules of thumb that have been derived from reflective practice. This chapter illustrates that the color theory is clearly not one thing to all people, as it is understood in very different ways, both in terms of its theoretical foundations as well as the complexity of its applications. This probably adds to the versatility of the theory. Bringing together key insights about the color theory for academics and practitioners, this chapter strives both to give a concise overview and to explore its richness.

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Research in Organizational Change and Development
Type: Book
ISBN: 978-1-78756-351-3

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Article
Publication date: 28 July 2022

Priyanka Sakare, Saroj Kumar Giri, Debabandya Mohapatra and Manoj Kr Tripathi

This paper aims to study the color change kinetics of lac dye in response to pH and food spoilage metabolites (ammonia, lactic acid and tyramine) for its potential application in…

187

Abstract

Purpose

This paper aims to study the color change kinetics of lac dye in response to pH and food spoilage metabolites (ammonia, lactic acid and tyramine) for its potential application in intelligent food packaging.

Design/methodology/approach

UV-Vis spectroscopy was used to study the color change of dye solution. Ratio of absorbance of dye solution at 528 nm (peak of ionized form) to absorbance at 488 nm (peak of unionized form) was used to study the color change. Color change kinetics was studied in terms of change in absorbance ratio (A528/A488) with time using zero- and first-order reaction kinetics. An indicator was prepared by incorporating lac dye in agarose membrane to validate the result of study for monitoring quality of raw milk.

Findings

Dye was orange-red in acidic medium (pH: 2 to 5) and exhibited absorbance peak at 488 nm. It turned purple in alkaline medium (pH: 7 to10) and exhibited absorbance peak at 528 nm. The change in absorbance ratio with pH followed zero-order model. Acid dissociation constant (pKa) of dye was found to be 6.3. Color change of dye in response to ammonia and tyramine followed zero-order reaction kinetics, whereas for lactic acid, the first-order model was found best. In the validation part, the color of the indicator label changed from purple to orange-red when the milk gets spoiled.

Originality/value

The study opens a new application area for lac dye. The results suggest that lac dye has potential to be used as an indicator in intelligent food packaging for detection of spoilage in seafood, meat, poultry and milk.

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Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

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Article
Publication date: 13 April 2023

Priyanka Sakare and Saroj Kumar Giri

The purpose of this paper was to study the color change kinetics of lac dye in response to aldehydes, carbon dioxide and other food spoilage metabolites for its potential…

90

Abstract

Purpose

The purpose of this paper was to study the color change kinetics of lac dye in response to aldehydes, carbon dioxide and other food spoilage metabolites for its potential application in intelligent food packaging.

Design/methodology/approach

UV–Vis spectroscopy was used to study the color change of dye solution. Ratio of absorbance of dye solution at 528 nm (peak of ionized form) to absorbance at 488 nm (peak of unionized form) was used to study the color change. Color change kinetics was studied in terms of change in absorbance ratio (A528/A488) with time using zero and first-order reaction kinetics. Lac dye-based indicator was prepared to validate the result of study for monitoring quality of strawberries.

Findings

Lac dye was orange-red in acidic medium and purple in alkaline medium. Color change of dye in response to benzaldehyde followed zero-order reaction kinetics, whereas for carbon dioxide first-order model was found best. No color change of dye solution was observed for alcohols, ketones and sulfur compounds. In the validation part, the color of the indicator label changed from purple to orange when the strawberries spoiled.

Originality/value

The study expands application area for lac dye as sensing reagent in intelligent food packaging for spoilage or ripeness detection of fruits and vegetables.

Details

Pigment & Resin Technology, vol. 53 no. 6
Type: Research Article
ISSN: 0369-9420

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Book part
Publication date: 18 August 2011

Leonard A. Valverde

A threefold approach is taken to provide understanding about the experiences that women of color have faced in their entry and upward advancement into administration in higher…

Abstract

A threefold approach is taken to provide understanding about the experiences that women of color have faced in their entry and upward advancement into administration in higher education institutions. The three overarching frameworks are historical, sociological, and organizational or institutional. The historical approach divides the chapter into three parts: the past (1960–1989), the present (1990–2010), and the future (2010 and beyond). Within these three time periods, major societal forces at work (during the specific time frame) will be used to help explain the extent and type of access women of color had within society's formal institutions. Since specific focus of the book/volume is on women of color in higher education, the third major tread is to reveal what and how university and colleges did to provide greater access and upward mobility for women of color or how such institutional action helped to impede.

Part I: The past shows that since and due to the Civil Rights Movement, women of color were preoccupied with access into higher education as students, faculty, and administrators. The past could rightly be termed the age of Tokenism (1960–1989). During the start, there were too few qualified women of color to be competitive for entry into faculty roles, let alone administrative positions. However, scarcity in numbers does not provide a full picture as to the slow access and low numbers. Instead, society's view was faulty, overly simplistic, and its intervention strategies hurt more than helped the situation. Particularly, the general thinking was that institutions were fair and okay, the problem lay with persons of color; they were disadvantaged in many ways, so they could not compete adequately. However, this one-sided view was biased and placed many unnecessary barriers for women of color and maintained favoritism and control for white males.

Part II: The present (1990–2010) demonstrates that progress by institutions of higher education (IHEs) to include women of color into administration was better but still unnecessarily slow and remained inadequate. While the initial strategies of affirmative action and blaming the victim for their plight were insufficient in the past, dynamics in society changed drastically in the present stage. Primarily, business in the United States, because of world competition, looked inward and out of necessity fundamentally reengineered itself. This one sweeping social dynamic caused traditionally discriminated groups to call for higher education to examine itself. In so doing, institutional racism was exposed and emphasized. No longer were women of color having to fit the white male mode for acceptance, and the customary “rites of passage” were questioned and altered, along with other practices. With a larger qualified pool of women of color due to past efforts, and to a larger extent a more level playing field in higher education, women of color enhanced their status. More importantly, the stage is now set for a much brighter future.

Part III: The future promises to be better for all: women of color, higher education, future generation of students, and society. Even though the conditions higher education institutions are facing are more difficult and the negative trends likely to persist, women of color can make great advances provided they capitalize on the events and assume some different roles. Specifically, it is proposed that women of color should actualize their natural leadership styles of participatory and transformational; they act as agents of change; and make a concerted effort to mentor and network younger women of color. Underlining the promise of a better future is that women of color know how to overcome hardships and they are better able to redesign institutions, change outdated practices, and shape the future of IHEs to fit the new paradigms. To date, on a microlevel this is what they have done to be personally successful, surely they can work on the macrolevel to make for stronger and effective IHEs.

Details

Women of Color in Higher Education: Turbulent Past, Promising Future
Type: Book
ISBN: 978-1-78052-169-5

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Article
Publication date: 14 August 2018

A. Shams Nateri, Sheida Zandi, Vahid Motaghitalab and Negin Piri

This paper aims to investigate the effect of titanium dioxide (TiO2) nanoparticle coating on the visible reflectance and color appearance of dyed cotton fabrics.

119

Abstract

Purpose

This paper aims to investigate the effect of titanium dioxide (TiO2) nanoparticle coating on the visible reflectance and color appearance of dyed cotton fabrics.

Design/methodology/approach

A Taguchi experimental design model was used to minimize the number of samples and for accurate prediction of possible responses. The governing parameters affecting the color change of dyed fabrics through the coating process were selected as shade of cotton fabrics, depth of shade, concentration and size of TiO2 nanoparticles and concentration of citric acid. The Taguchi model suggests the L18 orthogonal array. In the meantime, the lower response category was selected to determine the optimum conditions. According to obtained results, coating with TiO2 nanoparticles results in color change (ΔEab*) of all dyed cotton fabrics.

Findings

The obtained results indicate that the TiO2-coated fabrics had higher reflectance compared to raw fabrics. Furthermore, it was found that the TiO2 pigmented coating increases the brightness of samples and simultaneously decreases their chroma. On the other hand, analysis of variance reveals that the concentration of TiO2 nanoparticles together with shade of fabrics has the most significant impact on the color change of dyed fabrics through coating process. Dye concentration and size of TiO2 particles also, to the same extent, had influence over the color change. However, the effect of the concentration of citric acid on the color change was insignificant.

Originality/value

This research investigates the effect of TiO2 nanoparticles on the optical property of colored fabric by using a Taguchi experimental design model to minimize the number of samples.

Details

Pigment & Resin Technology, vol. 47 no. 5
Type: Research Article
ISSN: 0369-9420

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Article
Publication date: 2 March 2012

Maja Stanic, Branka Lozo and Diana Gregor Svetec

The purpose of this paper is to evaluate and discuss colour properties, stability and lightfastness after accelerated exposure in xenon‐arc light apparatus, of 3D ink jet prints…

1303

Abstract

Purpose

The purpose of this paper is to evaluate and discuss colour properties, stability and lightfastness after accelerated exposure in xenon‐arc light apparatus, of 3D ink jet prints produced by using 3D colour printing process.

Design/methodology/approach

3D colour prints were produced using ZCorporation 3D printing method. The samples were divided into groups according to the finishing process applied (untreated, finished with different infiltrants). Colorimetric properties were measured using spectrophotometer. Samples were placed into xenon‐arc based weathering apparatus (Xenotest), using the preset glass filtered sunlight, standard indoor conditions. Colour stability was evaluated as change in colour after repeating the spectrophotometer measurements and comparing spectral and specific colorimetric values of initial and exposed samples.

Findings

Based on methodology used, the analysis has shown the changes in colour appearance of differently finished 3D prints, which were mostly attributed to chroma and lightness variations. The colour stability of samples studied noticeably varied and is dependent on colour, percentage of ink coverage and finishing method. Issues of colour and stability of 3D ink jet prints could become important as 3D printing emerges into new application areas, in which the object properties will need to be maintained for a certain amount of time.

Research limitations/implications

The research is comparative and is limited to the specific materials and procedures used.

Originality/value

The paper describes aspects of colour 3D printing for which the published research and literature data are still, for the most part, lacking. Colour measurements methodology and evaluation of stability described could be of value for further research and for users of the technology.

Details

Rapid Prototyping Journal, vol. 18 no. 2
Type: Research Article
ISSN: 1355-2546

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Article
Publication date: 27 September 2023

Siddhesh Umesh Mestry, Vardhan B. Satalkar and S.T. Mhaske

This study aims to describe the design and synthesis of two novel azo and imine chromophores-based dyes derived from two different aldehydes with intramolecular colour matching…

122

Abstract

Purpose

This study aims to describe the design and synthesis of two novel azo and imine chromophores-based dyes derived from two different aldehydes with intramolecular colour matching that are pH sensitive.

Design/methodology/approach

The visible absorption wavelength (λmax) was extended when azo chromophore was included in imine-based systems. The dyed patterns created sophisticated colour-changing paper packaging sensors with pH-sensitive chromophores using alum as a mediator or mordant. Due to the tight adhesive bonding, the dyes on paper’s cellulose fibres could not be removed by ordinary water even at extremely high or low pH, which was confirmed by scanning electron microscopy analysis. The dyed patterns demonstrated an evident, sensitive and fast colour-changing mechanism with varying pH, from pale yellow to red for Dye-I and from pale yellow to brown-violet for Dye-II.

Findings

The λmax for colour changing was recorded from 400 to 490 nm for Dye-I, whereas from 400 to 520 for Dye-II. The freshness judgement of food was checked using actual experiments with cooked crab spoilage, where the cooked crab was incubated at 37 oC for 6 h to see the noticeable colour change from yellow to brown-violet with Dye-II. The colour-changing mechanism was studied with Fourier transform infrared (FTIR) spectra at different pH, and thin layer chromatography, nuclear magnetic resonance and FTIR spectroscopy studied the desired structure formation of the dyes. Potential uses for smart packaging sensors include quickly detecting food freshness during transportation or right before consumption.

Originality/value

1. Two novel azo-imine dyes have been synthesized with a pH-responsive effect. 2. The pH-responsive mechanism was studied. 3. The study was supported by computational chemistry using density functional theory. 4. The obtained dyes were used to make pH-responsive sensors for seafood packaging to judge the freshness.

Details

Pigment & Resin Technology, vol. 53 no. 6
Type: Research Article
ISSN: 0369-9420

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Article
Publication date: 6 July 2015

Haibao Lu, Yongtao Yao and Long Lin

This paper aims to create and to study multifunctional shape memory polymer (SMP) composites having temperature-sensing and actuating capabilities by embedding thermochromic…

427

Abstract

Purpose

This paper aims to create and to study multifunctional shape memory polymer (SMP) composites having temperature-sensing and actuating capabilities by embedding thermochromic particles within the polymer matrix.

Design/methodology/approach

The multifunctional materials were fabricated following a process consisting of blending (of the thermochromic particles and the SMP at various ratios), mixing, degasing, moulding and thermal curing, prepared by incorporating thermochromic particles within the polymer. The effect of the thermochromic particles on the thermomechanical properties and thermally responsive shape memory effect of the resulting multifunction SMP composites were characterised and interpreted.

Findings

It was found that exposure of the composites to temperatures above 70°C led to a pronounced change of their colour that was recorded by the thermal and electrical actuation approaches and was reproducibly reversible. It was also found that the colour of the composites was independent of the mechanical state of the SMP. Such effects enabled monitoring of the onset of the set/release temperature of the SMP matrix. Furthermore, the combination of thermochromic additive and the SMP resulted in significantly improved thermomechanical strength, absorption of infrared radiation and the temperature distribution of the SMP composites.

Research limitations/implications

The temperature-sensing and actuating capabilities of the polymeric shape memory composites developed through this study will help to extend the field of potential applications of such composites to fields including sensors, actuators, security labels and information dissemination, where colour indication is an advantageous feature.

Originality/value

The SMP composites capable of temperature sensing and actuating are novel.

Details

Pigment & Resin Technology, vol. 44 no. 4
Type: Research Article
ISSN: 0369-9420

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Article
Publication date: 6 September 2023

Hafsat T. Rumah, Mansur B. Ibrahim and Sani M. Gumel

The purpose of this research is to identify and investigate some natural dyes with halochromic properties for potential use as food spoilage indicators to reduce waste and curve…

78

Abstract

Purpose

The purpose of this research is to identify and investigate some natural dyes with halochromic properties for potential use as food spoilage indicators to reduce waste and curve the negative effects of food borne diseases.

Design/methodology/approach

Exactly 10 potential dye-yielding plants were selected based on their colour (mostly purple, red, maroon and pink). Solvent extraction was used to extract the dyes and pH differential method was used to determine the concentrations of anthocyanin in the extracted dyes. Different concentrations of hydrochloric acid and sodium hydroxide (0.1 M, 1 M and 2 M) in drops and in excess as acidic and basic solution, respectively, were used to test the halochromicity of the extracted dyes. Methyl red (a synthetic dye) was used as a reference standard/control. The pH of the dyes was recorded before and after addition of both NaOH and HCl solutions.

Findings

Five out of the 10 dyes extracted (labelled as dye A–E for Ti plant (green Cordyline fruticosa), coleus (Coleus blumei), paper flower (Bougainvillea glabra), painted nettle (Palisandra coleus) and purple heart (Setcresea purpurea), respectively, were found to be halochromic (even at low doses) by changing its colour when exposed to both acidic and basic solutions. While other dyes labelled F–J for red acalypha (Acalypha wilkesiana), golden shower (Cassia fistula), golden dew drop (Duranta repens), wild sage (Lantana camara var Aculeata) and pink oleander (Apocynaceae Nerium oleander), respectively, were either completely insensitive to the solutions in drops, slightly sensitive at high doses or the colour change is insignificant. Although some dyes were found to be more sensitive than others but in most cases, the colour changes in halochromic dyes were more stable in acidic conditions than in basic making it more sensitive to the basic than the acidic solution with the exception of dye A and E (to some extent) which was sensitive to both acidic and basic solution. The anthocyanin contents of dye A–J were found to be between the range of 2.28–10.35 mg/l with dye E having the lowest and dye J with the highest anthocyanin concentration, respectively. The initial pH of all the dyes falls within the range of 4.8–7.3 with most found within the acidic range.

Originality/value

Halochromic dye research studies are still at the infancy stage in developing world despite the vast available and abundant potential natural halochromic dye-yielding plants. The study explored this area of research and gives an opportunity for the development of smart packaging for pH-sensitive foods using natural dyes as an alternative to conventional synthetic dyes to reduce cost and also curve the negative effect of synthetic dyes as well as food borne diseases.

Details

Pigment & Resin Technology, vol. 53 no. 6
Type: Research Article
ISSN: 0369-9420

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Article
Publication date: 5 July 2013

Paul A. Watters

A key problem in money laundering investigations based on open source intelligence gathering is the performance (efficiency and accuracy) of people in the team, where suspects…

922

Abstract

Purpose

A key problem in money laundering investigations based on open source intelligence gathering is the performance (efficiency and accuracy) of people in the team, where suspects will typically try to conceal incriminating evidence or deliberately deceive investigators to avoid prosecution. If we are able to develop a suitable psychological model of deception for web‐based investigations, it should be possible to develop training programmes to improve investigators' ability to “see beyond” deliberate concealment. The purpose of this paper is to empirically test a model based on non‐linear system identification using a well‐known psychological phenomenon (the Stroop effect), where conflicting colour and text information is presented to subjects which they are instructed to process in a certain way.

Design/methodology/approach

The paper uses an experimental approach.

Findings

The results indicate that strategies for improving investigator information processing performance can benefit from models that incorporate both linear and non‐linear components.

Originality/value

Although the Stroop effect is well known, no other papers have investigated how it may be used to evaluate and monitor the performance of investigators. The real value of this study will emerge when tools are developed to better train investigators to identify concealment within conflicting input data.

Details

Journal of Money Laundering Control, vol. 16 no. 3
Type: Research Article
ISSN: 1368-5201

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