Guimei Wang, Shaohua Jin, Buqin Zhang, Fugui Yang and Xiaoli Ji
The coal reserves overlain by buildings, water bodies and railways are estimated to be about 14 billion tons in China. Based on the concept of green mining, in order to save the…
Abstract
The coal reserves overlain by buildings, water bodies and railways are estimated to be about 14 billion tons in China. Based on the concept of green mining, in order to save the unit energy, Double pumps in parallel forms of pumping are adopted in 0the paste filling of the pumping system. The optimal solution of the objective function could be obtained by taking the unit flow power of the pumping system as the objective function, using the quadratic polynomial by the least square method curve fitting and by the application of MATLAB. Thereby it is possible to reduce power consumption and increase the efficiency of the operating economy in the paste filling station.
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Abstract
Purpose
The flammability of epoxy resin is a major disadvantage in applications that require flame resistance. Epoxy monomers and hardeners containing flame-retardant elements are molecularly incorporated in the resin network are expected to exhibit better flame resistance than those borne on an additive approach. In recent years, because of health and environmental regulation, the use of waterborne coatings has received many attentions. However, waterborne epoxy resin curing agent with excellent flame retardancy has been seldom reported. The paper aims to study the preparation of waterborne P-N-containing epoxy resin curing agent and its performances (P-N – phosphorous and nitrogen).
Design/methodology/approach
Waterborne P-N-containing epoxy curing agent was prepared in this study using reactive flame retardant 10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-xa-10-phosphaphenanthrene-10-oxide, liquid epoxy resin, triethylenetetramine and butyl glycidyl ether at the mole ratio of 1.0:2.0:2.0:2.0.
Findings
The results show that the epoxy thermoset from the prepared P-N-containing curing agent presents good flame retardancy and can pass the V-1 rating, and the cured epoxy thermoset film presents excellent performances such as water resistance, adhesion, impact resistance and pencil hardness. This study provides useful suggestions for the application of the water-borne flame retardancy epoxy resins in coating industry.
Research limitations/implications
Each step of products during the preparation of waterborne P-N-containing epoxy curing agent cannot be accurately tested.
Originality/value
This method for synthesis of waterborne P-N-containing epoxy curing agent is novel and could be used for various applications in epoxy coating industry.