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The purpose of this study is to verify the possibility of applying alumina (Al2O3) as the passivation and antireflective coating in silicon solar cells.
Abstract
Purpose
The purpose of this study is to verify the possibility of applying alumina (Al2O3) as the passivation and antireflective coating in silicon solar cells.
Design/methodology/approach
Model of a studied structure contains the following layers: Al2O3/n+/n-type Si/p+/Al2O3. Optical parameters of the aluminium oxide films on silicon wafers were measured in the range of wavelengths from 250 to 1,400 nm with a spectrophotometer Perkin Elmer Lambda 900. The minority carrier lifetime at the start of the n-type Si base material and after each of the next technological process was analysed by a quasi-steady-state photoconductance technique. The electrical parameters of the solar cells fabricated with four different thickness of the Al2O3 layer were determined on the basis of the current-voltage (I-V) characteristics. The silicon solar cells of 25 cm2 area and 300 µm thickness were investigated.
Findings
The optimum thickness of alumina as passivation layer is 90 nm. However, considering also antireflective properties of the first layer of a photovoltaic cell, the best structure is silicon with alumina passivation layer of 30 nm thickness and with TiO2 antireflective coatings of 60 nm thickness. Such solution has allowed to produce the cells with the fill factor of 0.77 and open circuit voltage of 618 mV.
Originality/value
Measurements confirmed the possibility of applying the Al2O3 as a passivation and antireflective coating (obtained by atomic layer deposition method) for improving the efficiency of solar cells.
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Keywords
Barbara Swatowska, Piotr Panek, Dagmara Michoń and Aleksandra Drygała
The purpose of this study was the comparison and analysis of the electrical parameters of two kinds of silicon solar cells (mono- and multicrystalline) of different emitter…
Abstract
Purpose
The purpose of this study was the comparison and analysis of the electrical parameters of two kinds of silicon solar cells (mono- and multicrystalline) of different emitter resistance.
Design/methodology/approach
By controlling of diffusion parameters, silicon mono- (Cz-Si) and multicrystalline (mc-Si) solar cells with different emitter resistance values were produced – 22 and 48 Ω/□. On the basis of current-voltage measurements of cells and contact resistance mapping, the properties of final solar cells based on two different materials were compared. Additionally, the influence of temperature on PV cells efficiency and open circuit voltage (Uoc) were investigated. The PC1D simulation was useful to determine spectral dependence of external quantum efficiency of solar cells with different emitter resistance. The silicon solar cells of 25 cm2 area and 240 µm thickness were investigated.
Findings
Considering the all stages of cell technology, the best structure is silicon solar cell with sheet resistance (Rsheet) of 45-48 Ω/□. Producing of an emitter with this resistance allowed to obtain cells with a fill factor between 0.725 and 0.758, Uoc between 585 and 612 mV, short circuit current (Isc) between 724 and 820 mA.
Originality/value
Measurements and analysis confirmed that mono- and multicrystalline silicon solar cells with 48 Ω/□ emitter resistance have better parameters than cells with Rsheet of 22 Ω/□. The contact resistance is the highest for mc-Si with Rsheet of 48 Ω/□ and reaches the value 3.8 Ωcm.
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Grzegorz Wroblewski, Konrad Kielbasinski, Barbara Swatowska, Janusz Jaglarz, Konstanty Marszalek, Tomasz Stapinski and Malgorzata Jakubowska
The paper aims to present the research results related to transparent heating elements made from carbon nanomaterials. Heating elements were fabricated only with cost-effective…
Abstract
Purpose
The paper aims to present the research results related to transparent heating elements made from carbon nanomaterials. Heating elements were fabricated only with cost-effective techniques with the aim to be easily implemented in large area applications. Presented materials and methods are an interesting alternative to vacuum deposition of transparent resistive layers and etching of low-resistive patterns. Fabricated heating elements were designed to be used as de-icing structures in roof-top windows.
Design/methodology/approach
The paper presents the research results related to transparent heating elements made from carbon nanomaterials. Heating elements were fabricated only with cost-effective techniques with the aim to be easily implemented in large area applications. Presented materials and methods are an interesting alternative to vacuum deposition of transparent resistive layers and etching of low-resistive patterns. Fabricated heating elements were designed to be used as de-icing structures in roof-top windows.
Findings
The sheet resistance of obtained layers was between 9 and 11 kΩ/□; however, double-walled carbon nanotubes showed significantly higher optical transmission (around 70 per cent) than graphene nanoplatelets (around 55 per cent for visible and near infrared range). The amount of polymer resin had the influence on the paints stability, electrical properties and coatings adhesion.
Originality/value
Results show a novel method of fabrication of a large area and transparent heating elements with tunable resistance done through the change of spray coating paint composition.
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