Youssef L. Nashed, Fouad Zahran, Mohamed Adel Youssef, Manal G. Mohamed and Azza M. Mazrouaa
The purpose of this study is to examine how well reinforced concrete structures can be shielded against concrete carbonation using anti-carbonation coatings based on synthetic…
Abstract
Purpose
The purpose of this study is to examine how well reinforced concrete structures can be shielded against concrete carbonation using anti-carbonation coatings based on synthetic polymer.
Design/methodology/approach
Applying free radical polymerization, an acrylate terpolymer emulsion that a surfactant had stabilized was created. A thermogravimetric analysis, minimum film-forming temperature, Fourier transform infrared spectroscopy and particle size distribution are used to characterize the prepared eco-friendly water base acrylate terpolymer emulsion. Using three different percentages of the acrylate terpolymer emulsion produced, 35%, 45% and 55%, the anti-carbonation coating was formed. Tensile strength, tensile strain, elongation, crack-bridging ability, carbon dioxide permeability, chloride ion diffusion, average pull-off adhesion strength, water vapor transmission, gloss, wet scrub resistance, QUV/weathering and storage stability are the characteristics of the anti-carbonation coating.
Findings
The formulated acrylate terpolymer emulsion enhances anti-carbonation coating performance in CO2 permeability, Cl-diffusion, crack bridging, pull-off adhesion strength and water vapor transmission. The formed coating based on the formulated acrylate terpolymer emulsion performed better than its commercial counterpart.
Practical implications
To protect the steel embedded in concrete from corrosion and increase the life span of concrete, the surface of cement is treated with an anti-carbonation coating based on synthetic acrylate terpolymer emulsion.
Social implications
In addition to saving lives from building collapse, it maintains the infrastructure for the long run.
Originality/value
The anti-carbonation coating, which is based on the synthetic acrylate terpolymer emulsion, is environmentally benign and stops the entry of carbon dioxide and chlorides, which are the main causes of steel corrosion in concrete.
Details
Keywords
Nader L. Labib, Fouad Zahran, Mohamed Adel Youssef, Azza M. Mazrouaa and Manal Gamal Mohamed
This study aims to extend the pot life without altering the qualities and performance of the coating, which is important to increase when manufacturing polyurethane coatings.
Abstract
Purpose
This study aims to extend the pot life without altering the qualities and performance of the coating, which is important to increase when manufacturing polyurethane coatings.
Design/methodology/approach
An acrylic polyol from a mixture of different monomers of hydroxypropyl methacrylate, methacrylic acid, 2-ethylhexyl acrylate, methyl methacrylate and n-butyl methacrylate was prepared with different ratios of 2,4-pentanedione as a pot life extender. The reaction takes place in presence of di-tert-butyl peroxide as initiator with samples (T1–T7). The physical properties of prepared acrylic polyol were characterized. Then, coating polyurethane varnish was prepared from the prepared acrylic polyol with an aliphatic polyisocyanate in a 1:1 equivalent ratio of OH:NCO at room temperature, in presence of paint thinner (diluents/solvent) and dibutyltin dilaurate as a catalyst to give samples (T1C–T7C). This coating was evaluated via Fourier-transform infrared spectroscopy, drying time, hardness and gloss, distinctness of image and reflected image quality.
Findings
The coating has a prolonged pot life while still maintaining the other qualities, thanks to the greater 2,4-pentanedione content.
Originality/value
It is desired to have a paint which has a satisfactory pot life, short curing time and reduces many drawbacks such as inefficient working and deterioration of the paint before application.