Mohammed Elalaoui Belghiti, Ayssar Nahlé, Abdeslam Ansari, Yasser Karzazi, S. Tighadouini, Yassir El Ouadi, A. Dafali, Belkheir Hammouti and Smaail Radi
This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss…
Abstract
Purpose
This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss, electrochemical impedance spectroscopy, and Tafel polarization measurements.
Design/methodology/approach
Weight loss measurements, potentiodynamic tests, electrochemical impedance spectroscopy, X-ray diffraction and spectral and conformational isomers analysis of A (E-PAA) and B (Z-PAA) were performed were investigated.
Findings
2-pyridinealdazine (PAA) acts as a good inhibitor for the corrosion of steel in 2.0 M H3PO4. The inhibition efficiency increases with an increase in inhibitor concentration but decreases with an increase in temperature.
Originality/value
This paper is intended to be added to the family of azines which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.
Details
Keywords
Asmae Bouoidina, Mehdi Chaouch, Abdelfattah Abdellaoui, Amal Lahkimi, Belkheir Hammouti, Fadoua El-Hajjaji, Mustapha Taleb and Ayssar Nahle
The inhibition effect of Foeniculum vulgare seeds’ (FVS) extract on the corrosion of mild steel in acidic medium was studied using weight loss, electrochemical impedance…
Abstract
Purpose
The inhibition effect of Foeniculum vulgare seeds’ (FVS) extract on the corrosion of mild steel in acidic medium was studied using weight loss, electrochemical impedance spectroscopy and Tafel polarization, as well as the surface morphology of the mild steel.
Design/methodology/approach
Weight loss measurements, potentiodynamic tests, electrochemical impedance spectroscopy studies and gas chromatography/mass spectrometry and scanning electron microscopy analysis of FVS extract were performed.
Findings
FVS extract acts as a good inhibitor for the corrosion of mild steel in 1.0 M HCl. The inhibition efficiency increases with the increase in inhibitor concentration but decreases with the increase of temperature.
Practical implications
FVS extract was observed to play an important role in the corrosion inhibition of mild steel in acidic solution.
Originality/value
This paper is intended to be added to the family of green inhibitors which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.
Details
Keywords
Ayssar Nahle, Fadoua El-Hajjaji, Abdeslam Ghazoui, Nour-Eddine Benchat, Mustapha Taleb, Rafik Saddik, Abdelmalik Elaatiaoui, Mohammed Koudad and Belkheir Hammouti
The purpose of this paper is to study the inhibition effect of (6-phenyl-3-oxopyridazin-2-yl) acetohydrazide (GP4) on the corrosion of mild steel in acidic medium by gravimetric…
Abstract
Purpose
The purpose of this paper is to study the inhibition effect of (6-phenyl-3-oxopyridazin-2-yl) acetohydrazide (GP4) on the corrosion of mild steel in acidic medium by gravimetric measurements, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS).
Design/methodology/approach
Weight loss measurements, potentiodynamic tests and EIS were performed during this study.
Findings
(6-phenyl-3-oxopyridazin-2-yl) acetohydrazide (GP4) was found to be a very efficient inhibitor for mild steel in 1.0 M HCl solution, reaching about 85 per cent with inhibitor concentration 1.0 × 10-3 M at 303 K.
Practical implications
(6-phenyl-3-oxopyridazin-2-yl) acetohydrazide (GP4) was found to play an important role in the corrosion inhibition of mild steel in acidic solution.
Originality/value
This paper is intended to be added to the family of pyridazine derivatives which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.
Details
Keywords
Ayssar Nahlé, Maysoon Al‐Khayat, Ideisan Abu‐Abdoun and Ibrahim Abdel‐Rahman
The purpose of this paper is to study electrochemically and by weight loss experiments the effect of P,P′‐Bis (triphenylphosphonio) methyl benzophenone dibromide (TPPMB) on the…
Abstract
Purpose
The purpose of this paper is to study electrochemically and by weight loss experiments the effect of P,P′‐Bis (triphenylphosphonio) methyl benzophenone dibromide (TPPMB) on the corrosion inhibition of mild steel in 1.0M HCl solution, which will serve researchers in the field of corrosion.
Design/methodology/approach
Weight loss measurements were carried out on mild steel specimens in 1.0M HCl and in 1.0M HCl containing various concentrations (2×10−8M and 2×10−5M) of the laboratory synthesized TPPMB at temperatures ranging from 303 to 343 K.
Findings
TPPMB was found to be a highly efficient inhibitor for mild steel in 1.0M HCl solution, reaching about 98% at the concentration of 2×10−5M at 303 K, a concentration and temperature considered to be very moderate. The percentage of inhibition in the presence of this inhibitor was decreased with temperature which indicates that physical adsorption was the predominant inhibition mechanism because the quantity of adsorbed inhibitor decreases with increasing temperature.
Practical implications
This inhibitor could have application in industries, where hydrochloric acid solutions at elevated temperatures are used to remove scale and salts from steel surfaces, such as acid cleaning of tankage and pipeline, and may render dismantling unnecessary.
Originality/value
This paper is intended to be added to the family of phosphonium salt corrosion inhibitors which are highly efficient and can be employed in the area of corrosion prevention and control.
Details
Keywords
Ayssar Nahlé, Ideisan Abu‐Abdoun and Ibrahim Abdel‐Rahman
The purpose of this paper is to study electrochemically and by weight loss experiments the effect of 4‐vinylbenzyl triphenyl phosphonium chloride on the corrosion inhibition of…
Abstract
Purpose
The purpose of this paper is to study electrochemically and by weight loss experiments the effect of 4‐vinylbenzyl triphenyl phosphonium chloride on the corrosion inhibition of mild steel in 1.0 M HCl solution, which will serve researchers in the field of corrosion.
Design/methodology/approach
Electrochemical and weight loss measurements were carried out on carbon steel specimens in 1.0 M HCl and in 1.0 M HCl containing various concentrations (1.0 × 10−7 to 1.0 × 10−4 M) of the laboratory synthesized 4‐vinylbenzyl triphenyl phosphonium chloride at temperatures ranging from 303 to 343 K.
Findings
4‐vinylbenzyl triphenyl phosphonium chloride was found to be a highly efficient inhibitor for carbon steel in 1.0 M HCl solution, reaching about 99 per cent at the concentration of 1 × 10−4 M at room temperature and about 96 per cent at 303 K, a concentration and temperature considered to be very moderate. The percentage of inhibition in the presence of this inhibitor was decreased with temperature which indicates that physical adsorption was the predominant inhibition mechanism because the quantity of adsorbed inhibitor decreases with increasing temperature.
Practical implications
This inhibitor could have application in industries, where hydrochloric acid solutions at elevated temperatures are used to remove scale and salts from steel surfaces, such as acid cleaning of tankage and pipeline, and may render dismantling unnecessary.
Originality/value
This paper is intended to be added to the family of phosphonium salt corrosion inhibitors which are highly efficient and can be employed in the area of corrosion prevention and control.
Details
Keywords
Ayssar Nahlé, Ideisan Abu‐Abdoun and Ibrahim Abdel‐Rahman
To provide a novel synthesized stilbazole derivative as a corrosion inhibitor for researchers in the field of corrosion science.
Abstract
Purpose
To provide a novel synthesized stilbazole derivative as a corrosion inhibitor for researchers in the field of corrosion science.
Design/methodology/approach
Electrochemical corrosion measurements (tafel plots) were carried out in a 3‐electrode electrochemical cell on the mild steel electrode in 1.0 M HCl and in 1.0 M HCl containing various concentrations (1.0 × 10−7 M to 1.0 × 10−3 M) of the laboratory synthesized trans‐4‐hydroxy‐4'‐stilbazole.
Findings
The percentage inhibition of trans‐4‐hydroxy‐4'‐stilbazole on mild steel in 1 M HCl solution increased with the increase of concentration of that inhibitor. This percentage inhibition steeply increased from 10.11 percent (at 1.0 × 10−7 M) to 30.34 percent at 1.0 × 10−6 M. The slope of this increase slightly decreased at the concentration of 1.0 × 10−5 M to reach 39.61 percent. At higher concentrations, the increase of the percentage inhibition was steeper than the initial part, and reached 97.92 percent at 1.0 × 10−3 M.
Practical implications
This inhibitor could have application in industries, where hydrochloric acid solutions are used to remove scale and salts from steel surfaces, such as acid cleaning of tankage and pipeline and may render dismantling unnecessary.
Originality/value
This paper is intended to be the building block or the nucleus for a new family or group of stilbazole derivatives in electrochemical studies of corrosion inhibitors.
Details
Keywords
Ayssar Nahlé, Ibrahim Almaidoor and Ibrahim Abdel-Rahman
This study aims to study electrochemically and by weight-loss experiments the effect of UAE Rhazya Stricta Decne extract on the corrosion…
Abstract
Purpose
This study aims to study electrochemically and by weight-loss experiments the effect of UAE Rhazya Stricta Decne extract on the corrosion inhibition of mild steel in 1.0 M HCl solution, which will serve researchers in the field of corrosion.
Design/methodology/approach
Weight loss measurements were carried out on mild steel specimens in 1.0 M HCl and in 1.0 M HCl containing various concentrations (ranging from 2.0 to 0.002 g/L.) of the UAE Rhazya Stricta Decne extract at temperatures ranging from 303 to 343 K.
Findings
The aqueous Rhazya Stricta Decne leaves extract was found to be a highly efficient inhibitor for mild steel in 1.0 M HCl solution, reaching about 90 per cent at 2.0 g/L and 303 K, a concentration considered to be very moderate. Even with one-tenth of that concentration, 0.2 g/L, an inhibition of about 82 per cent was obtained at 303 K. The rate of corrosion of the mild steel in 1.0 M HCl is a function of the concentration of the Rhazya Stricta Decne extract. This rate increases as the concentration of the Rhazya Stricta Decne extract is increased. The percentage of inhibition in the presence of this inhibitor was decreased with temperature which indicates that physical adsorption was the predominant inhibition mechanism because the quantity of adsorbed inhibitor decreases with increasing temperature.
Practical implications
This inhibitor could have application in industries, where HCl solutions at elevated temperatures are used to remove scale and salts from steel surfaces, such as acid cleaning of tankage and pipeline, and may render dismantling unnecessary.
Originality/value
This paper is intended to be added to the family of green corrosion inhibitors which are highly efficient and can be used in the area of corrosion prevention and control.
Details
Keywords
Wang Huilong, Zheng Jiashen and Liu Jing
The effectiveness of bisquaternary ammonium salt N,N′‐Bis(dodecyldimethyl)‐3‐oxa‐1,5‐ pentanediammonium dichloride used as corrosion inhibitor for carbon steel in 1.0 M HCl was…
Abstract
The effectiveness of bisquaternary ammonium salt N,N′‐Bis(dodecyldimethyl)‐3‐oxa‐1,5‐ pentanediammonium dichloride used as corrosion inhibitor for carbon steel in 1.0 M HCl was investigated by weight loss and electrochemical techniques. Surfaces were characterised by scanning electron microscopy. The performance of the bisquaternary ammonium salt was also compared with that of urotropine, a commercial corrosion inhibitor for acid media in industry practice. The results showed good inhibiting action of the inhibitor. The inhibition efficiency increases with the inhibitor concentration but is temperature–independent. N,N′‐Bis(dodecyldimethyl)‐3‐oxa‐1,5‐pentanediammonium dichloride acts mainly as a mixed‐type inhibitor. The inhibition of this bisquaternary ammonium compound was assumed to occur via adsorption of the inhibitor molecule on the metal surface without affecting the corrosion mechanisms. The adsorption of the inhibitor on the metal surface in HCl solution was found to obey Frumkin's isotherm.