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1 – 4 of 4Amruta Joglekar-Athavale, Ganapati Shankarling, Satishchandra Dubey, Vinita Deshpande, Bikashkumar Jaiswal and Arun Nayak
The spectrally selective solar absorption paint is prepared from spinel-based mixed metal oxides with inorganic binder as a key component. Inorganic binder (furnace cement) is…
Abstract
Purpose
The spectrally selective solar absorption paint is prepared from spinel-based mixed metal oxides with inorganic binder as a key component. Inorganic binder (furnace cement) is blended with mixed metal oxide pigment during synthesis. High temperature stability upto 1,100ºC is achieved by the use of this modified coating system. The purpose of this paper is to work on solar selective coating synthesis, and application of a coating as a water-borne paint is the additive key feature that helps in reduction of solvent use.
Design/methodology/approach
The paint was formulated using water-based system, and the main component of colorant was made by mixed metal oxide–based spinel pigment and highly temperature stable inorganic binder.
Findings
The paint formed shows excellent absorptive power with low emittance even at high temperature. Optical and thermal properties were determined along with adhesion, abrasion and other properties. The solar absorptance for these samples were as = 0.93–0.95 with corresponding thermal emittance of eT = 0.096 (at room temperature) and 0.2–0.22 (at elevated temperature 100°C).
Originality/value
The paint formed shows excellent absorptive power with low emittance even at high temperature. The paint can be applied in solar absorptive tower system. The obtained results indicated excellent thermal stability of prepared paint coatings. As inorganic binder was used, the paint has reduction in solvent use, and being water as a base, it is environment friendly, easy to apply and durable at high temperatures, as the binder itself is stable up to 1,500ºC.
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Amruta Joglekar-Athavale and Ganapti S. Shankarling
The review glances upon the colorants used for printing on ceramic substrates by ink jet technology and techniques, chemistry involved during the selection of the colorants.
Abstract
Purpose
The review glances upon the colorants used for printing on ceramic substrates by ink jet technology and techniques, chemistry involved during the selection of the colorants.
Design/methodology/approach
The ink jet technology is an easy and a convenient technique, specially designed colorants are used for such applications with tailor made properties and features.
Findings
New developments in technology and chemistry of colorants to achieve successes in application studies of ceramic substrates.
Research limitations/implications
N/A.
Practical implications
This review glances upon the history, development and practical approach of the current techniques with available dyes and pigments and the techniques involved during the synthesis and application.
Originality/value
The review paper provides information about the development of the inkjet technique on ceramics and available colorants with methods.
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Amruta Joglekar-Athavale and Ganapti S. Shankarling
A mixed metal oxide-based spinel ceramic pigment has been successfully synthesized incorporating inorganic, high-temperature stable furnace cement as an inbuilt binder. Step by…
Abstract
Purpose
A mixed metal oxide-based spinel ceramic pigment has been successfully synthesized incorporating inorganic, high-temperature stable furnace cement as an inbuilt binder. Step by step synthesis was done for the spinel and cement mix formulations.
Design/methodology/approach
The pigment mix was synthesized by a solid-solid method where the inorganic binder was incorporated in the mix. The results suggested that CoCuMn-based spinel ceramic pigment with cement mix could be obtained at an annealing temperature of 1,100ºC for 1 h and the size, morphology and crystallinity of spinel mix were greatly influenced by the calcination temperature.
Findings
The pigment mix synthesized was applied as a coating to different substrates such as aluminum, glass and Mild steel. The results revealed that spectral selectivity of TSSS paint coatings based on the CoMnCu spinel ceramic mix was much better than that of solvent-based coatings for high-temperature applications. The presence of cement as an inorganic binder makes the functioning and application of paint easy as it becomes that of a waterborne type.
Originality/value
Ease of application, stability at high temperatures, best absorptivity at the solar selective spectrum and excellent adhesion properties for the selected surface are the key features of the designed pigment system. The applied pigment mix was studied as a coating to get the results for solar selective system.
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Amruta Joglekar-Athavale and Ganapti S. Shankarling
This paper aims to propose a simple, effective and environmentally benign method for the synthesis of commercially important pigment copper phthalocyanine (PC) blue has been…
Abstract
Purpose
This paper aims to propose a simple, effective and environmentally benign method for the synthesis of commercially important pigment copper phthalocyanine (PC) blue has been developed using deep eutectic solvent (DES).
Design/methodology/approach
DES prepared from choline chloride and urea is used as a reaction medium, as well as a source of ammonia. The design of the experiment and factorial design study has proved that the milder reaction conditions with high yields and reusability of DES are the key features of the present study.
Findings
The synthesized pigment is obtained at milder reaction conditions with excellent yield, which can be seen from the design of experiments done for the optimization of results.
Practical implications
The synthesized pigment was used as a colorant in epoxy-based paint and in screen ink, which gave satisfactory results with respect to color values and stability.
Social implications
The screen ink prepared was formulated considering environmental aspects to avoid the use of solvents. Biodegradable components were added to the colorant to make the ink environment friendly.
Originality/value
Reactions occur at moderate temperatures without affecting the time factor, thus, it saves energy. A simple, effective and environmentally benign method for the synthesis of commercially important copper PC has been developed using DES. After the first batch, DES synthesized can be reused as a reaction medium where only a stoichiometric amount of urea is to be added. Simple work up, high yield and purity are achieved.
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