M.A. Abd El‐Ghaffar, A.Z. Gomaa, M.M. Abd El‐Malek, E.A.M. Youssef and A.A. Abd El‐Hakim
The corrosion protective properties of the primer films prepared from Egyptian manganese ore (high and medium grades) and epoxy resin have been determined by immersing coated…
Abstract
The corrosion protective properties of the primer films prepared from Egyptian manganese ore (high and medium grades) and epoxy resin have been determined by immersing coated films in artificial sea water for 28 days. The good corrosion protective properties indicate that the Egyptian manganese ore can be satisfactorily used in anticorrosive primer formulations for steel surface protection.
A.Z. Gomaa, M.M. Metwally, M. Moustafa and M.A. Abd El‐Ghaffar
Insecticides are chemicals that are used to control damage or annoyance from insects. Generally, control is achieved by poisoning the insects by oral ingestion of stomach poisons…
Abstract
Insecticides are chemicals that are used to control damage or annoyance from insects. Generally, control is achieved by poisoning the insects by oral ingestion of stomach poisons, by contact poisons that penetrate through the cuticle, or by fumigants that penetrate through the respiratory system. Pojurowsky Leon has made wall paper washproof and contact‐insecticidal coating compositions by addition of 1–12% insecticide solutions in polar organic solvents in 15–45% amounts by usual vinyl‐acrylic or oil type emulsion lacquers. Coating dye compositions dispersible, in water and containing (MeO)2P(O)CH(OH)CC13 with lasting insecticide effect were prepared by Bozzay Jazsel, et al. In 1986, Lee, et al, have performed aqueous emulsions of insecticidal activity, containing hydrophilic silicone organic copolymer elastomer. Recently Moustafa, M., et al prepared and evaluated various coating compositions for their insecticidal activity. The binders used are chlorinated rubber, polyurethane and alkyd resins. Three kinds of insecticides with trade names sumicidin, sumithion and cyanox were studied. Cockroaches were the target insect. They showed that compositions based on alkyd or chlorinated rubber and containing 4% cyanox or sumithion as insecticide showed promising results as insecticidal and insect repellent coatings.
M.A. Abd El‐Ghaffar, E.A.M. Youssef, M.M.H. Abo‐Shosa and N.A. Ibrahim
Modifies short and medium alkyd resins using perfluori‐nated urethane toluene isocyanate (PFUTI), and incorporates the modified resins in a set of paint formulations containing…
Abstract
Modifies short and medium alkyd resins using perfluori‐nated urethane toluene isocyanate (PFUTI), and incorporates the modified resins in a set of paint formulations containing different ratios of zinc phosphate as an inhibitive pigment. Achieves promising results and illustrates corrosion‐protective properties in various paint formulations and also a paint formulation free of the inhibitive pigment. Shows enhancement of the corrosion protection efficiencies by the improvement in the hydrophobicity of alkyd resin modified with PFUTI. In view of these results, minimizes or neglects the most expensive inhibitive pigments from an economical standpoint.
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A.A. Abd El‐Hakim, M.A. Abd El‐Ghaffar, M.M. Abd El‐Malek and E.A.M. Youssef
Results and discussion Adsorption isotherms of stearic acid on the surface of manganese ore samples:
Highly efficient heat‐resistant paint formulations based on Egyptian manganese ore (high and medium grades) and silicon resin were prepared. The heat‐resistance efficiency as well…
Abstract
Highly efficient heat‐resistant paint formulations based on Egyptian manganese ore (high and medium grades) and silicon resin were prepared. The heat‐resistance efficiency as well as the physico‐mechanical properties of the painted films were evaluated. Promising results were deduced, showing that manganese ore imparts heat‐resistance protection for painted substrate up to 450°C. The anticorrosive properties of these paint formulations were moderate but their efficiency as heat‐resistant anticorrosive paints was improved by adding 1 per cent of melamine to the paint constituents.
M.A. Abd El‐Ghaffar, E.A.M. Youssef, M.M.H. Abo‐Shosha and N.A. Ibrahim
Short and medium alkyd resins were modified using perfluorinated urethane toluene isocyanate (PFUTI). The modified resins were incorporated in a set of paint formulations…
Abstract
Short and medium alkyd resins were modified using perfluorinated urethane toluene isocyanate (PFUTI). The modified resins were incorporated in a set of paint formulations containing different ratios of zinc phosphate as an inhibitive pigment. Promising results were achieved and corrosion protective properties were illustrated in various paint formulations and also in a paint formulation free of the inhibitive pigment. The corrosion protection efficiencies were enhanced by the improvement in the hydrophobicity of alkyd resin modified with perfluorinated toluene isocyanate (PFUTI). These results encourage us to minimize or neglect the most expensive inhibitive pigments from the economic point of view.
M.M. Elsawy, Mohamed A. Awad, Nashwa M. Saleh and H. Abd El-Wahab
Paper aims to Preparation and evaluation of isoxazole benzene sulfonamide derivatives and incorporated it with waterborne household paints to develop coating compositions as an…
Abstract
Purpose
Paper aims to Preparation and evaluation of isoxazole benzene sulfonamide derivatives and incorporated it with waterborne household paints to develop coating compositions as an insecticidal coating against Musca domestica adults.
Design/methodology/approach
The synthesized compounds were prepared and confirmed by different analyzes, fourier transform infra-red (FTIR), mass, proton nuclear magnetic resonance (1HNMR) and Carbon 13 nuclear magnetic resonance (13CNMR) spectra. The prepared compound has been blended with waterborne household paint formulation, the physical and mechanical properties of the paint formulation has been studied. The efficiency of the isoxazole benzene sulfonamide derivatives when incorporated with waterborne paint against Culex quinquefasciatus and Mosquito house fly adults, also have been examined.
Findings
The obtained results of the paint formulations confirmed their best performance and providing good scrub resistance. Also, the finding promising results of the insecticide test of the paint formulation may be because of the biological activity of these compounds and containing sulfonamide, cyanide and free aromatic amine groups comparing with the standard recommended organophosphorus insecticide. The order activity increase with increasing the dose concentration of the isoxazole derivatives and the activity of chemical compounds itself is represented in terms of their medium lethal concentrations LC50 (LC90), which recorded 0.90(1.62), 0.89(1.61) and 0.86(1.56) g/ml for 5, 3 and 4 chemical compounds, respectively, after 72 h from treatment.
Practical implications
These types of organic compounds are friendly environmentally and can be used as a biocide with different types of paint formulations.
Originality/value
Insecticide waterborne household paints based on isoxazole benzene sulfonamide derivatives as insecticide agents are novel.
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Various rosin‐modified polyesteramide resins are formulated and evaluated for their insecticidal activity. Five kinds of pyrethroid and organophosphorus insecticides with trade…
Abstract
Various rosin‐modified polyesteramide resins are formulated and evaluated for their insecticidal activity. Five kinds of pyrethroid and organophosphorus insecticides with trade names Neo‐Pynamin Forte, Gokilaht, Neo‐Pynamin, Sumithrin and Cyanox are studies. American Cockroaches (Periplaneta americana) are the target insect.
SAID T. GOMAA, MOHAMMED H. BALUCH, HAMDY H. ABDEL‐RAHMAN and AMMAR K. MOHAMMED
A finite element formulation for flexure of isotropic plates based on a recent refined theory is developed. The refined theory incorporates effects of transverse shear, transverse…
Abstract
A finite element formulation for flexure of isotropic plates based on a recent refined theory is developed. The refined theory incorporates effects of transverse shear, transverse normal stress and transverse normal strain. The Galerkin finite element method was used to develop the finite element equations for both plate bending and inplane problems. The performance of the proposed finite element model was evaluated by solving problems of uniformly loaded thick plates with different support conditions. The results of the present formulation are compared with Mindlin/Reissner and elasticity solutions.
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M.A. Abd El‐Ghaffar, E.A.M. Youssef and N.M. Ahmed
Historically, paints designed to protect steel and other metals have been formulated using anticorrosive chromate pigments, which are currently under environmental restrictions…
Abstract
Historically, paints designed to protect steel and other metals have been formulated using anticorrosive chromate pigments, which are currently under environmental restrictions. During the investigation reported here, various phosphate compounds. The pigments prepared were characterised using a variety of chemical and spectrophotometric methods of analysis including emission atomic absorption, transmission electron microscope, X‐ray diffraction, in addition to thermal gravimetric analysis. The pigments were also evaluated according to relevant international standard testing methods. The phosphates prepared were incorporated into anticorrosive paint formulations, to replace the imported zinc phosphate pigment, containing medium oil alkyd resin, and melamine formaldehyde resin. Paint films obtained were tested in artificial seawater for 28 days for anticorrosion properties. The results indicated that the paint films had good anticorrosive protection properties that could be attributed to the pigments prepared and the resins used.