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The purpose of this study is to investigate the effect of the incorporated zirconia (ZrO₂) nanoparticles on the performance of the deposited layer Ni–Cu alloy on steel sheet.

The aim was to produce Ni–Cu–ZrO₂ nanocomposite coatings by electrodeposition technique and estimate the influence of ZrO2 nanoparticles on the performance of Ni–Cu alloy. The surface morphologies and chemical compositions of the deposited layers were assessed using scanning electron microscopy and energy-dispersive X-ray analysis, respectively. Nanoindentation was used as a well-advanced technique for measuring microhardness and Young’s modulus values of different coatings. The corrosion resistance in 3.5 per cent NaCl solution of electrodeposited films has been investigated.

The main conclusion is that the surface morphologies of Ni–Cu–ZrO2 nanocomposite coatings were fine granular compared with Ni–Cu alloy. The corrosion behavior illustrated that the incorporation of ZrO₂ nanoparticles with Ni–Cu film improved the corrosion resistance. Significant improvement was also demonstrated in the hardness of nanocomposite coatings.

The optimized industrial use of steel-coated Ni–Cu alloy with super properties. Consequently, a social benefit can be associated with the reduction in the corrosion rate and increases the microhardness and Young’s modulus.

The results presented in this work are an insight into understanding the incorporation of ceramic reinforcement with metal or alloy films (matrix) on carbon steel using the electrodeposition technique. The development of corrosion resistance of Ni–Cu alloys has been considered as a promising behavior. In this work, a consistent assessment of the results achieved on laboratory scale has been conducted.

The aim of this work was to investigate how Andrographis paniculata (Burm.f.) Wall.ex Nees extract affected the corrosion of low-carbon (C) steel in 0.1M HCl.

The Andrographis paniculata (Burm.f.) Wall.ex Nees was extracted into distilled water at 70°C for 1 h. The corrosion inhibition efficiency of the extract was determined in 0.1M HCl using weight loss measurements, potentiodynamic polarization and electrochemical impedance spectroscopy. The effects of extract concentrations and of temperature were investigated.

The Andrographis paniculata (Burm.f.) Wall.ex Nees extract could inhibit the corrosion process of low-C steel in 0.1M HCl. With the extract concentration of 1 g/l, an inhibition efficiency of 96.3 per cent was obtained. The extract acted as an anodic inhibitor. The adsorption process of the extract was physisorption and it followed the Langmuir adsorption isotherm.

This paper revealed that Andrographis paniculata (Burm.f.) Wall.ex Nees cultivated in Thailand, which was extracted using a simple and environmentally friendly method, could act as a very good green corrosion inhibitor for low-C steel in 0.1M HCl solution.

The purpose of this paper is to study the ability of commercial tara powder to convert rust into iron tannate and evaluate their use as raw material for the formulation of water based rust converter.

Water-borne acrylic primers were formulated with tara powder and aqueous tara extract and applied on steel rusted by three different methods. The conversion of rusted steel by tara tannins was studied by X-ray diffraction spectroscopy, infrared spectroscopy and scanning electron microscopy. The acrylic primers, containing hydrolysable tannins, were coated with alkyd finish and were evaluated in comparison to commercial systems in accelerated corrosion tests. The corrosion inhibition effects of tara powder on mild steel in 0.1M NaCl were studied by DC electrochemical techniques.

Tara tannin converts rust to ferric tannate and increases the magnetite content of rusted steel. The water-based acrylic primer formulated with aqueous extract of tara, alkyd-coated finish, showed performance equivalent to pure alkyd system.

The chlorides content in the commercial tara powder can be screened the beneficial effect of hydrolysable tannins to convert rust. Furthermore, the water-based rust converter formulated with acrylic resin may be sensitive to salt contamination of rust.

Hydrolysable tannins from commercial tara powder have not been studied yet in its application to the development of rust converters. A water-based primer formulated with commercial tara powder developed for the effective treatment of rusted surfaces can be of interest as an environmentally friendly to current commercial approaches.

The purpose of this paper is to make people aware of organic corrosion inhibitors.

As it is a literature review paper, no specific method is used.

It has been found that plant extracts and oils show inhibition efficiency up to 98 percent, so it is certain that plant extracts and oils are effective corrosion inhibitors and can be successfully used at the industrial level.

Plant extracts and oils are also found to be non‐toxic, highly efficient, renewable and cheap. But less effort has been given towards the identification of which compound is active in the extract.

The paper shows detailed account of the inhibitors obtained from plants, which are used as natural corrosion inhibitors.

The purpose of this research paper was to investigate the use of methanolic extract of Salvia hispanica (S. hispanica) as a green corrosion inhibitor for bronze in a simulated acid rain solution.

Extract of S. hispanica was used as a green corrosion inhibitor for bronze in simulated acid rain solution. Electrochemical techniques such as potentiodynamic polarization curves, electrochemical impedance spectroscopy and electrochemical noise were used. Parameters such as polarization, charge transfer and noise resistance (Rp, Rct and Rn, respectively) were calculated.

Results showed that the extract acts as a good, anodic type of inhibitor. The inhibitor efficiency increased with increasing its concentration up to 400 ppm, decreasing beyond this concentration. Efficiency also increased with an increase in the immersion time. The inhibition was due to the adsorption of components found in the S. hispanica extract following a Langmuir adsorption isotherm.

S. hispanica extract can be used as a corrosion inhibitor for bronze in acid rain solution.

This study provides new information on the inhibition features of S. hispanica under specific conditions. This eco-friendly inhibitor could find applications to protect bronze exposed to polluted urban atmospheres.

To study the effects of the sodium salts of molybdate, tungstate and monovanadate as well as some derivatives of Neville‐Winter acid azo dyes on the corrosion of carbon steel in 3.5 percent NaCl solution.

Open circuit potential measurement and potentiostatic polarization techniques have been used.

It was found that all the compounds had inhibition effects on carbon steel dissolution. Inhibition efficiency (IE) increased with increase in inhibitor concentration. The process of inhibition was attributed to the formation of an adsorbed film on the metal surface, which protects the metal against the corrosive medium. The adsorption of these compounds on the steel/chloride interface was found to follow Freundlich adsorption isotherm behaviour.

Proves the effectiveness of the sodium salts of molybdate, tungstate and monovanadate as well as some derivatives of Neville‐Winter acid azo dyes on the corrosion of carbon steel in 3.5 percent NaCl solution.

The paper reports an investigation into the use of aqueous extracts of rice bran as a green inhibitor for corrosion of carbon steel in hydrochloric acid (HCl) solution.

Extracts from the rice bran were used as the main component of an environmentally friendly corrosion inhibitor for use in HCl pickling processes. Inhibition behavior on carbon steel in HCl was investigated by means of mass‐loss tests, polarization curves, electrochemical impedance spectroscopy and atomic force microscopy.

The results show that the extract exhibited good inhibition performance in 1 M HCl. The inhibition efficiency increased with increase in the concentration of the inhibitor and was only moderately affected by temperature variations in the range 303‐363 K. The inhibitive action was due to adsorption on the A3 steel and the adsorption process was consistent with the Langmuir isotherm. The free energy of adsorption (ΔG_ads.) was −4.192 kJ/mol. The negative value of ΔG_ads. indicated spontaneous adsorption of the inhibitor occurred on the surface of A3 steel.

Rice bran extract is an effective inhibitor and can be used to protect carbon steel from corrosion in HCl solution.

The rice bran extracts are an effective green inhibitor and can be widely used in the pickling of metals.

The purpose of this investigation is to study the corrosion inhibition of carbon steel (CS) using a “green” inhibitor, Opuntia ficus-indica, in an aerated, 0.5 M H₂SO₄ solution at different concentrations and temperatures.

Weight loss determinations, surface studies, electrochemical impedance spectroscopy and potentiodynamic polarization were applied during the investigation.

It was observed that Opuntia ficus-indica extract can decrease the corrosion rate of CS, and its efficiency increases with increasing concentration up to 1,000 ppm and with time, but decreases with increasing the temperature from 25 to 600C. The inhibitory activity is due to the presence of phenolic compounds in its chemical structure.

The work was done under static conditions, whereas in acid cleaning conditions, there is a dynamic system. However, the findings may apply to both the systems.

CS is used in acidic environments in the acid cleaning industry.

Results of this work show that it is possible to reduce the cost of repair of equipment and the environmental impact of corrosion.

There are very few investigations on the study of Opuntia ficus-indica leaf extract as a green inhibitor in an acidic environment.

This paper aims to evaluate the ability of Aubepine and Molokhia extract, obtained by cathodic electrochemical treatment (CET), to protect steel rebar against attack by chloride ions in environment of reinforced concrete marine structures. The effect of Aubepine and Molokhia extract was investigated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques.

This experimental work has achieved particularity to compare the behaviour of two types of treatment (carbon steel treated one time by Aubepine extract and one time by Molokhia extract) submitted to the presence and absence of chloride ions.

The results obtained show that the extract solution of the plant could serve as an effective inhibitor for the corrosion of steel. Inhibition was found to increase with increasing concentration of Molokhia extract and for Aubepine extract maximum concentration is 1 g/L.

Plant extracts and traditional medicinal herbs have become important as an environmentally acceptable, readily available and renewable source for wide range of inhibitors.

Aubepine and Molokhia extract are novel green plants extract as corrosion inhibiting coating for steel embedded in concrete. Aubepine is a genus of trees in the family Rosaceae and Molokhia is the leaves of Corchorus olitorius. Flavonoids content was found in both of Aubepine and Molokhia extract as green inhibitors for corrosion of metals.

The purpose of this paper is to evaluate the corrosion inhibition potential of mangrove (Rhizopora apiculata) tannin in hydrochloric acid medium on copper with the view of developing a natural corrosion inhibitor.

The mangrove tannin was extracted from the mangrove bark and its anticorrosion potential was studied by weight loss, electrochemical and scanning electron microscopy (SEM) analysis.

It has been found that the mangrove tannin effectively inhibits the corrosion on copper metal in hydrochloric acid solution. The results of the electrochemical and weight loss methods showed that the inhibition efficiency of mangrove tannin increases with increasing its concentration. Inhibition is achieved through the adsorption of tannin molecules onto the copper surface and the adsorption follows the Langmuir adsorption isotherm model. SEM study also supports the adsorption of the inhibitor molecules onto the copper surface.

In this paper, mangrove tannin has been studied for the first time as a potential copper corrosion inhibitor in hydrochloric acid medium. The anticorrosion effect of tannin has been proven by standard methods. This natural inhibitor could find use in industries where copper is used as a fabrication metal.