Wael Mohamed Abdelmaksoud, Mohamed Aboaly, Said Teleb, Adel Mohy-Eldin Gabr and Mostafa Abdellah Sayed
The pursuit of manufacturing new inks with low financial cost is an urgent economic demand. Thus, the purpose of this paper is to synthesize some new pigments derived from Lithol…
Abstract
Purpose
The pursuit of manufacturing new inks with low financial cost is an urgent economic demand. Thus, the purpose of this paper is to synthesize some new pigments derived from Lithol Rubine (LR) via a successful simple route and to investigate their physicochemical properties for usage in the inks industry.
Design/methodology/approach
Two novel pigments were generated during the reaction of LR with Mn(II) and Co(II) salts in ethanolic solutions. The obtained pigments were isolated as solid compounds and characterized through elemental analysis, UV–vis, Fourier transform infrared, 1H NMR spectra, oil absorption, specific gravity, melting point, molar conductivity and magnetic moment measurements. Their dyeing and durability characteristics were examined using American Standard Testing Methods. The synthesized pigments were then applied in inks formulation.
Findings
The printing inks containing the two new pigments (LR–Mn and LR–Co) were compared to (GF 59-606 and GF 59-616), respectively. The results of this study showed that the performance of newly prepared pigments was comparable to that of commercial pigments currently in use in the inks industry.
Practical implications
LR and its new derivative pigments can be used in other different applications such as paper coating, crayon, rubber and paint industries.
Originality/value
The authors designed an efficient synthesis for some novel pigments. The synthesis technique is featured by a short reaction time, high yields and ease of use. The pigments developed would be good and cost-effective substitute for the original commercially available and expensive pigments used in the inks industry.
Details
Keywords
Xiao Wang, Xuan Liang, Bo Wang, Chang-qing Guo, Shan-gui Zhang, Kai Yang, Shi-ya Shao, Yan Sun, Zheng Guo, Xue-yan Yu, Donghai Zhang, Tai-jiang Gui, Wei Lu, Ming-liang Sun and Rui Ding
The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty…
Abstract
Purpose
The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty anticorrosion coatings, zinc-rich coatings provided cathodic protection for the substrate. However, to ensure cathodic protection, a large number of zinc powder made the penetration resistance known as the weakness of zinc-rich coatings. Therefore, graphene and basalt flakes were introduced into zinc-rich coatings to coordinate its cathodic protection and shielding performance.
Design/methodology/approach
Three kinds of coatings were prepared; they were graphene modified zinc-rich coatings, basalt flakes modified zinc-rich coatings and graphene-basalt flakes modified zinc-rich coatings. The anticorrosion behavior of painted steel was studied by using the electrochemical impedance spectroscopy (EIS) technique in chloride solutions. The equivalent circuit methods were used for EIS analysis to obtain the electrode process structure of the coated steel system. Simultaneously, the corrosion resistance of the three coatings was evaluated by water resistance test, salt water resistance test and salt spray test.
Findings
The study found that the addition of a small amount of graphene and basalt flakes significantly improved the anticorrosion performance of coatings by enhancing their shielding ability against corrosive media and increasing the resistance of the electrochemical reaction. The modified coatings exhibited higher water resistance, salt water resistance and salt spray resistance. The graphene-basalt flakes modified zinc-rich coatings demonstrated the best anticorrosion effect. The presence of basalt scales and graphene oxide in the coatings significantly reduced the water content and slowed down the water penetration rate in the coatings, thus prolonging the coating life and improving anticorrosion effects. The modification of zinc-rich coatings with graphene and basalt flakes improved the utilization rate of zinc powder and the shielding property of coatings against corrosive media, thus strengthening the protective effect on steel structures and prolonging the service life of anticorrosion coatings.
Originality/value
The significance of developing graphene-basalt flakes modified zinc-rich coatings lies in their potential to offer superior performance in corrosive environments, leading to prolonged service life of metallic structures, reduced maintenance costs and a safer working environment. Furthermore, such coatings can be used in various industrial applications, including bridges, pipelines and offshore structures, among others.
Details
Keywords
Osama A. G. Wahba, Ali M. Hassan, H. Abd El-wahab, A. Mohy-Eldin, A.M. Naser and Osama A. Fouad
The purpose of this paper is to investigate the synthesis of calcium-based group of mixed metal oxide (MMO) pigments. The evaluation of these pigments as heat and corrosion…
Abstract
Purpose
The purpose of this paper is to investigate the synthesis of calcium-based group of mixed metal oxide (MMO) pigments. The evaluation of these pigments as heat and corrosion resistant was also explored.
Design/methodology/approach
Two simple synthesis techniques, namely, co-precipitation and solid-state calcination method, were used to synthesise nanosized MMO pigments. And then the physico-chemical requirements according to standards for the synthesised pigments are investigated.
Findings
The prepared MMO pigments were mainly in the single phase double oxide forms. The prepared oxides exhibited good heat (up to 600°C) and corrosion resistance properties (in 5 per cent NaCl for 500 h).
Research limitations/implications
This paper investigates the physico-chemical properties of synthesised calcium-based group of MMO pigments. And then evaluate it as heat and corrosion resistant paints. The simple techniques used for synthesis of nanosized MMO pigments will significantly improve the research and development of pigments’ structure and performance.
Practical implications
Calcium-based MMO pigments can be used as heat and corrosion resistant pigments. The easy synthesis of the mixed oxide pigments will open the door for further vital special industrial uses and applications.
Originality/value
Low cost, simple techniques and using naturally abundant material can be used for mass production of some other low-cost nanosized materials.
Details
Keywords
Merve Engin, Sinan Sönmez and Öznur Özden
The purpose of this paper is to investigate the influences of coating colours and their contents on the fundamental properties of base papers and also evaluate these results in…
Abstract
Purpose
The purpose of this paper is to investigate the influences of coating colours and their contents on the fundamental properties of base papers and also evaluate these results in terms of mechanical and wood-free papers.
Design/methodology/approach
A design research approach has been based on the application of various coating colours and analysis of mechanical and optical tests results of the coated mechanical and wood-free base papers.
Findings
This study is confirmed that the coating colours can be easily applied to the surface of the papers. The experimental data have revealed that significant improvements exist in the values of tear resistance (strength), brightness and opacity of the mechanical base papers, especially by the application of the coating colours including kaolin pigment. The results show that mechanical papers can also be used in areas with high brightness expectations by applying coating colour.
Originality/value
The originality of this work is based on understanding and comparing the effects of applying similar coating formulations on mechanical and wood-free base papers.
Details
Keywords
H. Abd El-Wahab, A.M. Hassan, A.M. Naser, O.A. Fouad, A.M. El-Din and O.A.G. Wahba
The purpose of this paper was to prepare and evaluate a nanosized mixed calcium iron oxide as a high heat-resistant pigment. Heat-resistant pigments can be defined as chemical…
Abstract
Purpose
The purpose of this paper was to prepare and evaluate a nanosized mixed calcium iron oxide as a high heat-resistant pigment. Heat-resistant pigments can be defined as chemical substances that impart color to a substrate or binder and retain their color and finish at elevated temperatures. Mixed metal oxides have been widely used as pigments in coating formulations.
Design/methodology/approach
This work presents synthesis of nanosized calcium iron oxide as an inorganic pigment by using simple synthesis technique, namely, solid-state calcination method, to study its heat and corrosion resistance. The prepared pigment was characterized by using X-ray diffraction, infrared spectroscopy, scanning electron microscopy and inductive coupling plasma. It was incorporated into paint formulations, and the heat, corrosion and mechanical resistance of dry paint film was evaluated.
Findings
In this work, the prepared calcium iron oxide pigment showed excellent heat and corrosion resistance.
Research limitations/implications
Heat-resistant coatings are required for industrial applications, mainly for reactors, exhaust pipes, space craft, stacks and similar equipments that are permanently and occasionally exposed to elevated temperatures. It was previously quite difficult to formulate heat-resistant organic coatings because of binder deficiencies; new vehicles for such applications are now available. Thus, the development of silicon resins has markedly advanced the utility of heat-resistant paints. High-temperature pigments are inorganic chemical compounds that impart and retain their color and finish to a substrate or binder at elevated temperatures.
Practical implications
The nanosized mixed calcium iron oxide could be used as a pigment in paint formulations. It was found that it significantly enhances the heat, corrosion and mechanical resistance. It can also find numerous applications in other paint formulations for surface coating.
Originality/value
The paper shows how the pigment consisting nanosized mixed calcium iron oxide could be used in heat-resistant paint formulations for coating metal surfaces.