Search results

To evaluate the effect of flux, activator and co‐activator on solid state synthesis of SrAl₂O₄: Eu^2 +, Dy^3 + phosphor, where boric oxide, europium oxide and dispersium oxide were used, respectively.

To optimise synthesis condition of long lasting phosphorescence SrAl₂O₄ phosphor, boric oxide was used as a flux. To improve relative intensity of SrAl₂O₄: Eu^2 + phosphor, the critical concentration of Eu^2 + was determined. The effect of various concentration of co‐activator on afterglow properties, the effect of Dy^3 + ion on the emission and excitation spectra were examined.

The SrAl₂O₄: Eu^2 +, Dy^3 + phosphor powders have been synthesised by solid state reaction method. The result of XRD patterns indicated that, addition of 5 mol% B₂O₃ enhanced the formation of SrAl₂O₄ at 1,200°C. Investigation on the variation of emission intensity of different phosphors containing different amounts of Eu^2 + revealed that after 6 mol% of Eu^2 + concentration, quenching process occurred. Dy^3 + formed trap levels and results demonstrated that increasing concentration of Dy^3 + up to 5 mol% reduced the relative intensity and increased the decay time.

Using B₂O₃ as a flux and solid state reaction method for preparation of this phosphor is in good agreement with industrial production and make it economic, because of reduced sintering temperature.

The purpose of this paper is to evaluate the effect of copolymer and starting material concentrations in homogeneous precipitation synthesis of Yttria nanoparticles and red‐emitting nanophosphors Y₂O₃:Eu³⁺. N‐isopropylacrylamide and acrylic acid (NIPAM/AAc) and urea are used.

To optimise synthesis condition of Y₂O₃:Eu³⁺ nanophosphor NIPAM/AAc copolymer was used as a modifier and the effect of various concentration of yttrium ions, urea and precipitation time on size, morphology and emission spectra were investigated.

Using NIPAM/AAc copolymer shows significant improvement on size and dispersion of nanoparticles. It is found that yttrium concentration, varying between 0.006 and 0.03 M, has a profound impact on the average size of particles, which systematically increases from 65 to over 165 nm. The rate of precipitation reaction, however, is shown to be independent of yttrium concentration. In contrast, as urea concentration increases from 0.2 to 5 M, the average particle size exhibits a gradual decrease from 183 to 70 nm. At extremely high urea concentration such as 5 M, a significant level of inter‐particle agglomeration is observed.

Based on this paper, the authors have successfully prepared some promising nanophosphors. The nanoparticles are studied by X‐ray diffraction, transmission electronic microscopy, zeta sizer, Infra red and photoluminescence spectroscopy.

The purpose of this paper is to investigate the effect of boric acid as a flux on the formation of the akermanite phase and optical properties of SrMgSi₂O₇:Eu,Dy phosphors.

The silicate‐based phosphor is prepared by sol‐gel method. Sr(NO₃)₂, Mg(NO₃)₂ · 6H₂O, Dy₂O₃, Eu₂O₃, are added to distilled water in their stoichiometric ratio, the obtained solution are mixed with H₃BO₃ (in the range of 0.01‐0.5 mol%) and a polymeric compound TESO (C₈H₂O₄Si). At the end, the phase composition and optical properties are investigated using X‐ray diffraction (XRD) and spectrophotometer analysis, respectively.

The XRD results showed that the akermanite (Sr₂MgSi₂O₇) is the only crystalline phase which is detected in the sample containing 0.05 mol% boric acid. Increasing of boric acid does not have a great effect on the XRD patterns intensity. Spectrophotometer analysis results show three maximum at 365, 395 and 430 nm on the excitation spectra. It also shows intensity of the excitation and emission spectra increased by adding boric acid up to 0.25 mol% and a sudden drop at 0.5 mol% boric acid.

Using boric acid as a flux, enhances formation of akermanite phase at lower temperature with desirable optical properties and a cost‐benefit way for industrial production. In this research, optimum value of boric acid was determined using XRD data, emission and excitation spectra.

Long afterglow Sr₂MgSi₂O₇ (SMS) phosphor was prepared by Douby's methods at high temperature and reductive atmosphere. The excitation and emission spectra of this phosphor showed that both had broad bands and that the main emission peak at 469 nm was due to 4f‐5d transitions of Eu⁺² and implied that the luminescence centres Eu⁺² occupied the Sr⁺² sites in the Sr₂MgSi₂O₇ host. The phosphor doped only with Eu ions did not demonstrate the long afterglow phenomenon, but when co‐doped with Dy⁺³ ions in the SMS matrix, significant long afterglow was observed.

The purpose of this research is as follows: DPP-BOH-PVA has been synthesized from 1,1′:3′,1″-terphenyl-5'-boronic acid (DPP-OH) and polyvinyl alcohol (PVA). The afterglow lifetime of DPP-BOH-PVA was studied by changing contents of DPP-OH (1, 2 and 4 Wt.%). These films were characterized with Fourier transform infrared, X-ray diffraction as structural analysis and DSC as thermal analysis. Afterglow lifetimes were evaluated as time-resolved emission decay profile analysis. Fiber films of DPP-BOH-PVA-2-E have been prepared by electrospinning method with the diameter of 5 μm and afterglow life time of 2.1 s (@ 535 nm) under ambient conditions. Stimulus responsive properties with afterglow emission for fiber film were investigated.

During the synthesis of the polymer, modification was carried out using DPP-OH/PVA with a molar ratio of 1/4, under an alkalinity medium with ammonium hydroxide and with a temperature of 80°C.

XRD results indicate that DPP-BOH-PVA film had high crystallinity, which is crucial for preparing organic room temperature phosphorescence (RTP) materials.

The reaction mixture must be stirred continuously. Temperature should be controlled to prevent the rapid evaporation of ammonium hydroxide.

This study provides technical information for the synthesis of multidimensional stimulation response RTP micron fiber thin film. The electrospinning technology may also promote the applications of the large areas of RTP films.

This resin will be used for the multidimensional stimulation response RTP fiber thin film.

The diameter of fiber film of PP-BOH-PVA-2-E by electrospinning method was in the range of 5 μm, and its afterglow lifetime decayed to be 2.1 s.

The purpose of this paper is to report on a study which aims to improve the compatibility of the long afterglow phosphors SrMgAl₄O₈:Eu²⁺, Dy³⁺with organic matrix, including its water resistance.

The phosphors were modified by the lauric acid‐based Al‐Zr coupling agent (CA). Then, they were characterised by attenuated total reflection fourier transform infrared (ATR‐FTIR), pH and electric conductivity in water, scanning electron microscope (SEM), contact angle and fluorescence decay curves before and after modification.

The pH and electric conductivity displayed the improved water resistance, as the Al‐Zr CA addition increased, and the minimum contact angle with resin decreased from 68.3 to 40.3°C, which showed that the compatibility with organic matrix was enhanced significantly. The afterglow luminous properties were unimpaired.

The researchers are encouraged to test the proposed method and enhance the compatibility further.

This method will extend the applications of phosphors in the paint, coatings, ink and plastics industry.

This paper introduces the lauric acid‐based Al‐Zr CA to modify the luminescent pigments of long afterglow phosphors; it can be also applied to other inorganic powders.

The purpose of this paper is to improve the anti‐sedimentation of the acrylic resin containing long afterglow phosphors (SrMgAl₄O₈:Eu²⁺, Dy³⁺).

The phosphors were first modified by the vinylsilane coupling agent MPS (3‐(methacryloxypropyl)‐trimethoxysilane). Then, the acrylic resin containing modified phosphors was synthesised by in situ polymerisation. Meanwhile, the compared blend sample was prepared by pure acylic resin with no modified phosphors in the same content. When the two resins were coated on glass, the films were characterised by ATR‐FTIR, SEM and TGA. The sedimentation performances of liquid resins were also observed.

Results showed that anti‐sedimentation of acrylic resin with phosphors by in situ polymerisation was enhanced greatly, because the phosphors have been connected with the macromolecule chain, and dispersed homogeneously with no aggregation, so preventing its sedimentation.

Researchers are encouraged to test the proposed method and enhance the anti‐sedimentation further.

This method provides an idea to solve the problem of anti‐sedimentation in luminescent paint containing long afterglow phosphors in practical production and application.

This paper introduced the in situ polymerisation to enhance the anti‐sedimentation of acrylic resin containing long afterglow phosphors and it can be applied also to other inorganic powders.