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The inhibition efficiency of sodium gluconate (SG) in controlling corrosion of carbon steel immersed in the environment containing 60 ppm Cl^– has been evaluated in the presence and absence of Zn²⁺ by weight loss method. SG and Zn²⁺ show a synergistic effect. The protective film has been analysed by FTIR and fluorescence spectra. The protective film consists of Fe²⁺‐gluconate complex and Zn(OH)₂. The film is found to be UV‐fluorescent. The IE of the SG‐Zn²⁺ system increases in the presence of Na₂SO₄; but decreases in the presence of Na₂SO₃ and also in the presence of N‐cetyl‐N,N,N‐trimethyl ammonium bromide. This study reveals that the transporting phenomenon plays a larger role than the scavenging of dissolved oxygen.

To evaluate the inhibition efficiency (IE) of polyvinyl alcohol (PVA) in controlling the corrosion of carbon steel immersed in neutral aqueous solutions containing 60 ppm of Cl⁻, in the absence and presence of Zn²⁺. To investigate the influence of sodium sulphite (Na₂SO₃), sodium dodecyl sulphate (SDS), pH and duration of immersion on the IE of PVA‐Zn²⁺ system. To analyse the protective film formed on the metal surface.

The IE has been evaluated by weight loss method. The protective film was analysed by FTIR and fluorescence spectra.

A formulation consisting of 100 ppm of PVA and 75 ppm of Zn²⁺ offered 81 per cent IE to carbon steel immersed in a solution containing 60 ppm of Cl⁻. A synergistic effect on inhibition of a combination of PVA and Zn²⁺ was observed during the tests. The protective film consisted of the Fe²⁺‐PVA complex and Zn(OH)₂. It was found to be UV‐fluorescent. When SDS was added to the PVA‐Zn²⁺ system, the mixture showed maximum IE at the critical micelle concentration (200 ppm) of SDS (an anionic surfactant). The oxygen‐scavenging effect of Na₂SO₃ increased as the concentration of Na₂SO₃ was increased. At lower concentrations of Na₂SO₃, the transport of the inhibitors played a more major role than did the removal of dissolved oxygen. As the pH value was increased, the IE of the PVA‐Zn²⁺ system decreased. As the duration of immersion was increased, the IE was observed to decrease.

Electrochemical studies such as polarization and AC impedance spectra will enlighten more on the mechanistic aspects of corrosion inhibition.

If this study is carried out at high temperature under simulated conditions, the findings may find applications in cooling water systems.

The role of transport of inhibitors towards the metal surface from the bulk of the solution, formation of micelles by surfactants, removal of dissolved oxygen by oxygen scavenger, competition between formation of insoluble iron‐inhibitor complex on metal surface and formation of soluble iron chloride in influencing the inhibitive property has been investigated. The protective film was analysed by FTIR spectra and fluorescence spectra.

To determine the inhibition efficiency and adsorption characteristics of two water soluble polymers namely polyvinyl alcohol (PVA) and polyethyleneglycol (PGE) as corrosion inhibitors of mild steel in H₂SO₄.

The inhibition efficiencies of PVA and PEG were evaluated using the weight loss and hydrogen evolution techniques at 30‐60°C.

The inhibition efficiency (I per cent) of the inhibitors increased with increase in concentration and temperature. The inhibitors (PVA and PEG) were found to obey Temkin, Freundlich and Langmuir adsorption isotherms from the fit of the experimental data at all concentrations and temperatures studied. The phenomenon of chemical adsorption is proposed from the activation parameters obtained. PEG was found to be a better inhibitor than PVA.

The mechanistic aspect of the corrosion inhibition can be better understood using electrochemical studies such as polarization and AC impedance spectra.

The findings may be useful in cooling water systems in industries under simulated conditions.

This paper provides additional new information on the inhibiting characteristics of PVA and PEG as promising corrosion inhibitors.

The purpose of this paper is to make people aware of organic corrosion inhibitors.

As it is a literature review paper, no specific method is used.

It has been found that plant extracts and oils show inhibition efficiency up to 98 percent, so it is certain that plant extracts and oils are effective corrosion inhibitors and can be successfully used at the industrial level.

Plant extracts and oils are also found to be non‐toxic, highly efficient, renewable and cheap. But less effort has been given towards the identification of which compound is active in the extract.

The paper shows detailed account of the inhibitors obtained from plants, which are used as natural corrosion inhibitors.

Explicit barriers to international trade, investment, technology, and financial flows have been reduced considerably. As a result, “macro-liberalization” of international economic transactions has largely run its course. Now, attention needs to shift from international rules for governments to international rules dealing with the various aspects of the international operations of firms – what are called “micro-issues” in this chapter; these include, by way of example, cross-border mergers and acquisitions and international bankruptcies. Such international rules for the principal actors in international production and markets would complement (or replace) the unilateral rules that exist at the national level. International rules would set the direct parameters for certain aspects of the international activities of firms and hence provide the global governance for operating in the global production and trading spaces. This chapter exemplifies for a number of areas the state of rule-making for some micro-issues, analyzes the nature of this rule-making, and suggests a way forward. Developing international micro-regulatory frameworks of rules of the road for the various aspects of the international operations of firms in the globalizing world economy should be the new frontier of international commercial diplomacy.

One of the existing and commonly used solar energy harvesting devices is the parabolic trough solar collector (PTSC). Because of their ability to operate in low and medium temperatures, parabolic trough concentrators are widely used in power generation plants and industrial process heating applications. Therefore, the investigation of how different operating conditions affect these devices’ overall efficiency has received a great deal of attention in the recent decade. This study aims to enhance the thermal performance of the PTSC and reduce the system cost.

In the novel configuration, a noncirculated nanofluid absorbs solar radiation through a glass wall. The base fluid was synthetic oil (5W30), and the nanoparticles used were copper oxide. The heat captured is immediately absorbed by the water circulating inside the copper tube immersed in the nanofluid. ANSYS FLUENT 15.0 was used for carrying out computational fluid dynamics simulations for two models of single and triple copper tubes. The experimental results obtained from a test rig constructed for this purpose were compared with the numerical outcomes of the single copper tube model.

The findings of the simulation demonstrated that performance was superior for the single copper tube model over the triple copper tube model. The numerical findings of the single copper tube model were compared with the experimental results. The numerical and experimental results differed from 3.17% to 5.6%. Investigations were carried out to study the effects of varying the volumetric flow rate of (20, 40, 60 and 80 L/h) and water inlet temperatures of (300, 315 and 330 K) on the effectiveness and performance of the newly developed model. Additionally, two nanofluid volume fractions of 0.05% and 0.075% were used for investigating their effect on the performance of the novel configuration. According to the findings, the highest thermal efficiency of 55.31% was recorded at 0.075% concentration and 80 L/h volume flow rate.

In this study, a novel direct absorption solar collector configuration using a noncirculated nanofluid was designed to enhance the thermal efficiency of PTSC. This new approach makes it possible to boost the thermal performance of the PTSC and lower the system’s cost.