There is a rising demand for high-performance 3D printed objects that have established potential applications in the sector of dental, automotive, electronics, aerospace, etc…
Abstract
Purpose
There is a rising demand for high-performance 3D printed objects that have established potential applications in the sector of dental, automotive, electronics, aerospace, etc. Thus, to meet the requirements of high-performance 3D printed objects, this study has synthesized, formulated and applied a resorcinol epoxy acrylate (REA) oligomer to a stereolithography (SLA) 3D printer.
Design/methodology/approach
Different formulations were developed by blending reactive diluents in the concentration of 10%, 15% and 20%, along with the fixed quantity of photo-initiators in the REA oligomer. The structure of synthesized REA oligomer was confirmed using 13 C nuclear magnetic resonance (NMR) and 1H NMR spectroscopy, and the rheological properties for prepared REA formulations were also evaluated. The ultraviolet (UV)-cured specimens of all REA formulations were thoroughly examined based on physical, chemical, optical, mechanical and thermal properties. The best suitable formulation was selected for SLA 3D printing.
Findings
As perceived, UV cured REA specimens exhibit superior mechanical, chemical and thermal properties, portraying the ability to use as a high-performance material. The increase in the concentration of reactive diluents indicated a significant improvement in the properties of REA resin. The 20% diluted formulation achieved excellent compatibility with a SLA 3D printer; thus, 3D objects are cast with good dimensional stability and printability.
Originality/value
Resorcinol-based resins have always been a key additive used to enhance properties in the coating and tire industry. In a new attempt UV, curable REA has been applied to a SLA 3D printer to cast high-performance 3D printed objects.
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Manzoor A. Khawaja and Mahmoud M. Aban
Studies samples of different used lubricating oils. Details how their physico‐chemical characteristics were determined by the use of modern instrumental analytical techniques; and…
Abstract
Studies samples of different used lubricating oils. Details how their physico‐chemical characteristics were determined by the use of modern instrumental analytical techniques; and how different standard separation techniques were used to separate the unused base oil and other components from the collected samples for characterization. Discusses the different re‐refining procedures available in the literature and highlights the merits and demerits of different re‐refining techniques. Concludes that re‐refining of used oil will conserve resources and help to preserve the environment.
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Summarizes the different techniques for the removal of conformal coatings from printed circuit boards and other electronic assemblies. Addresses each of the four techniques for…
Abstract
Summarizes the different techniques for the removal of conformal coatings from printed circuit boards and other electronic assemblies. Addresses each of the four techniques for the removal of conformal coating (thermal, mechanical, chemical and abrasive), along with how they work with each type of conformal coating (urethane, acrylic, silicone, epoxy, parylene and UV curable coatings). Also provides summaries for the removal times and clean up for each technique.
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This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl…
Abstract
Purpose
This study aims to focus on how reactive diluents with mono- and di-functionalities affect the properties of resin formulation developed from bioderived precursors. A hydroxyethyl methacrylate (HEMA) terminated urethane acrylate oligomer was synthesized and characterized to study its application in stereolithography 3D printing with different ratios of isobornyl acrylate and hexanediol diacrylate.
Design/methodology/approach
Polyester polyol was synthesized from suberic acid and butanediol. Additionally, isophorone diisocyanate, polyester polyol and HEMA were used to create urethane acrylate oligomer. Fourier transform infrared spectroscopy and 1H NMR were used to characterize the polyester polyol and oligomer. Various formulations were created by combining oligomer with reactive diluents in concentrations ranging from 0% to 30% by weight and curing with ultraviolet (UV) radiation. The cured coatings and 3D printed specimens were then evaluated for their properties.
Findings
The findings revealed an improvement in thermal stability, contact angle value, tensile strength and surface properties of the product which indicated its suitability for use as a 3D printing material.
Originality/value
This study discusses how oligomers that have been cured by UV radiation with mono- and difunctional reactive diluents give excellent coating characteristics and demonstrate suitability and stability for 3D printing applications.
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Sobiya Manzoor, Syed Zameer Hussain, Tawheed Amin, Omar Bashir, Bazila Naseer, Abida Jabeen, Ufaq Fayaz, Naseh Nisar, Aarizoo Mushtaq, Monisa Yousouf, Zahida Naseem and Uzznain Khan
The purpose of this article was to highlight the various methods of extrusion technologies for encapsulation of bioactive components (BACs).
Abstract
Purpose
The purpose of this article was to highlight the various methods of extrusion technologies for encapsulation of bioactive components (BACs).
Design/methodology/approach
BACs provide numerous health-care benefits; however, downsides, including a strong effect of organoleptic properties by reason of the bitterness and acridity of a few components, and also a short shelf-life, limit their application in food. The food industry is still demanding complicated qualities from food ingredients, which were often impossible to obtain without encapsulation such as stability, delayed release, thermal protection and an acceptable sensory profile. Various techniques such as melt injection extrusion, hot-melt extrusion, electrostatic extrusion, co-extrusion and particles from gas-saturated solutions, could be used for maintaining these characteristics.
Findings
Extrusion technology has been well used for encapsulation of bioactive chemicals in an effort to avoid their numerous downsides and to boost their use in food. The count of BACs that could be encapsulated has risen owing to the extrusion technology just as form of encapsulation. Extrusion technique also aids in the devaluation of the fragment size of encapsulated BACs, allowing for greater application in the food business.
Originality/value
The study reported that encapsulating BACs makes them more stable in both the product itself and in the gastrointestinal tract, so using encapsulated BACs would result in a product with stronger preventive properties.
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About 30 years have passed since the initial work in the field of polyurethane compounds was begun. This work has resulted in a wide choice of materials for use in surface…
Abstract
About 30 years have passed since the initial work in the field of polyurethane compounds was begun. This work has resulted in a wide choice of materials for use in surface coatings. The commercial development of aliphatic urethane prepolymers during the past few years has made possible the formulation of exterior coatings with good weathering properties.
Salts of aluminium and calcium such as stearates, octoates and naphthenates, are used to impart structure to oleoresinous paints. Alternatively, aluminium alcohoiates can be used…
Abstract
Salts of aluminium and calcium such as stearates, octoates and naphthenates, are used to impart structure to oleoresinous paints. Alternatively, aluminium alcohoiates can be used as reactive intermediates which form salts by reaction with the medium. The use of these materials is generally restricted to flat or semi‐gloss paints and storage instability is sometimes encountered. A chlorinated rubber paint which contains titanium, kaolin, talc, a chloroparaffin plasticiser, and a solvent blend of hexyl acetate and xylene, is rendered thixotropic using a 1% level of aluminium stearate addition. The product is suitable for applying as thick corrosion‐resistant coatings to metals.
Haojia Su, Zhengchun Cai, Zhengwei lv, Yongkang Chen and Yongxin Ji
In this work, the authors used reversible addition-fragmentation transfer (RAFT) polymerization to develop a new cationic acrylate modified epoxy resin emulsion for water-borne…
Abstract
Purpose
In this work, the authors used reversible addition-fragmentation transfer (RAFT) polymerization to develop a new cationic acrylate modified epoxy resin emulsion for water-borne inkjet which have the advantages of both polyacrylate and epoxy resin. The emulsion was successfully used in the canvas coating for inkjet printing. This paper aims to contribute to the development of novel cationic emulsions for inkjet printing industry.
Design/methodology/approach
In this work, the epoxy acrylate was synthesized from RAFT agent and epoxy resin firstly. Cationic macromolecular emulsifier was prepared by RAFT polymerization, using 2,2’-Azobisisobutyronitrile as initiator, 2-(dimethylamino)ethyl methacrylate and styrene as monomer, which was directly used to prepare the emulsion. The influences of the amount of 2-(dimethylamino)ethyl methacrylate on particle size, zeta potential and water contact angle were studied. Finally, the cationic emulsion was used to print images by inkjet printing.
Findings
The emulsion has the smallest particle size, the highest potential and the highest water contact angle when the DM content is 13 Wt.%. The transmission electron microscopy analysis reveals the latex particles is core-shell sphere with the diameters in the range 120–200 nm. The emulsion was successfully used in the canvas coating for inkjet printing. This work will contribute to the development of novel cationic emulsions for inkjet printing industry.
Originality/value
The emulsion was successfully used in the canvas coating for inkjet printing. This work will contribute to the development of novel cationic emulsions for inkjet printing industry.
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Neda Mahami, Nasim Abedimanesh, Somayyeh Asghari, Kosar Mohammadnejad, Mohammad Reza Eskandari, Zivar Nejadebrahimi, Hassan Ahangar, Keivan Nedaei, Mojtaba Fathi, Ehsan Noori and Behrooz Motlagh
This study aims to evaluate the effects of betanin on AMP-activated protein kinase (AMPK), Sirtuin1 (SIRT1) and Sirtuin6 (SIRT6) gene expression as well as the tumour necrosis…
Abstract
Purpose
This study aims to evaluate the effects of betanin on AMP-activated protein kinase (AMPK), Sirtuin1 (SIRT1) and Sirtuin6 (SIRT6) gene expression as well as the tumour necrosis factor alpha (TNF-α) and interleukin 6 (IL-6) cytokine release in peripheral blood mononuclear cells (PBMCs) of patients with coronary artery disease (CAD) and healthy controls.
Design/methodology/approach
PBMCs isolated from whole blood of 50 patients with CAD and 48 healthy subjects aged 45 to 60 years were treated with 10 and 20 µM of betanin for 24 h. Real-time polymerase chain reaction was performed to assess gene expression levels of AMPK, SIRT1 and SIRT6. The supernatants of the cultured cells were used to assess the IL-6 and TNF-α protein levels by ELISA.
Findings
Treatment with both doses of betanin significantly increased AMPK, SIRT1 and SIRT6 expression in PBMCs of CAD patients compared to control non-treated cells (p < 0.05). In PBMCs of healthy subjects, only treatment with high dose of betanin showed significant increase in AMPK (p = 0.007), SIRT1 (p = 0.013) and SIRT6 (p = 0.024) expression compared to control non-treated cells. Betanin (20 µM) also significantly decreased TNF-α and IL-6 concentrations in the culture supernatants of the CAD patients compared to control non-treated cells (p < 0.001).
Originality/value
Betanin could enhance AMPK, SIRT1 and SIRT6 gene expressions in PBMCs and represent a useful complementary treatment to reduce the proinflammatory status accompanied with CAD.
Keeping pace with the new proprietary products offered each year are the new raw materials from which many of these are formulated.