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Article
Publication date: 17 December 2024

Ali A. Ali, Fatimah A.M. Al-Zahrani, Walid E. Elgammal, Mahmoud Ali, Ammar M. Mahmoud and H. Abd El-Wahab

This study aims to prepare some disperse dyes based on pyrazole derivatives and fully evaluate their use as azo-disperse dyes linked with pyrazolo[1,5-a] pyrimidine. This study…

Abstract

Purpose

This study aims to prepare some disperse dyes based on pyrazole derivatives and fully evaluate their use as azo-disperse dyes linked with pyrazolo[1,5-a] pyrimidine. This study aims to prepare dye polyester fabric at different conditions (pH and time) at a depth of 4% using a high-temperature pressure process in water.

Design/methodology/approach

The disperse dyes were created by dissolving enaminone and pyrazole derivatives in glacial acetic acid and fusing sodium acetate at reflux for 6 h. The chemical structure of the produced dye was studied using elemental analysis, Fourier-transform infrared spectroscopy, 1H NMR and 13C NMR spectroscopic analytical methods. The dyeing of Dispersed dyes 14–16 on polyester under diverse conditions was comprehensively investigated in this work.

Findings

The prepared Organic dyes 14–16 were found to be highly functional and suitable for this type of dyeing technique. High color strength is possessed by the materials dyed with Disperse dyes 14–16. Even in low alkaline conditions, these dyes exhibited a strong affinity for polyester fabric, changing just little in response to pH changes. The hue of the dyed polyester samples varied from beige to reddish brown and yellowish brown because of the coupler moieties.

Originality/value

This study is important because it offers novel dyes that may be used to dye polyethylene terephthalate fibers that exhibit remarkable brightness and levelness. It also offers a viable solution for creating a variety of colors in polyester fabrics.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 June 2024

H Radi, Khaled F. El-Nemr, Salwa M. Elmesallamy and Enas Amdeha

This study aims to prepare activated carbon (AC) and activated biochar (BC) from sugarcane bagasse (SCB) can be used as carbon black (CB) replacement for styrene butadiene rubber…

Abstract

Purpose

This study aims to prepare activated carbon (AC) and activated biochar (BC) from sugarcane bagasse (SCB) can be used as carbon black (CB) replacement for styrene butadiene rubber (SBR) composites cured by electron beam (EB) radiation.

Design/methodology/approach

This study is carried out to investigate the effect of partial replacement of CB (as traditional filler) by AC or BC prepared from low-cost agricultural wastes (SCB) to improve the properties of SBR rubber cured by EB radiation (doses from 25 to 150 kGy).

Findings

The results indicated that the addition of AC or BC leads to improve the physical and mechanical properties of SBR with increasing irradiation dose [especially at concentration of 10 parts per hundred part of rubber (phr) from BC]. Also in this study, this paper examines how exposure of SBR rubber composites to ultraviolet (UV) radiation changes the mechanical properties for these composites, to do that, the specimens were examined before and after they were exposed to UV radiation for 300 h. The results showed that, the irradiated SBR composites, UV exposure, exhibit better retention in mechanical properties as compared with unirradiated ones, and the samples loaded with CB hybrid with ACs had an increased value of tensile strength (TS) retention as compared with blank sample.

Originality/value

The importance of this study is that, the production of AC from SCB offers a huge opportunity to overcome the problem of the disposal of SCB.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

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