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Chemical treatability of dairy wastewater originating from a dairy and dairy products plant at Istanbul was investigated on the basis of chemical oxygen demand (COD) parameter as a pre‐treatment alternative. FeCl₃, FeSO₄ and alum were used as coagulants in the jar‐test experiments of four sets of daily composite wastewater samples taken once every month. The effect of acid cracking has also been searched through acid addition and pH adjustment. Characterisation studies demonstrated that wastewater characteristics varied within a wide range in spite of no significant production changes at the plant during the experimentation period. Optimum coagulant dosage has been determined as 200mg l^–1 for all the coagulants with the optimum pH values between 4 and 4.5 for FeCl₃ and FeSO₄, and 5‐6 for alum. Maximum overall COD removal efficiencies were obtained as 72 per cent, 59 per cent and 54 per cent for FeCl₃, FeSO₄ and alum, respectively. Nevertheless, COD removal efficiencies were found to be inadequate to meet the current discharge standards of Greater Metropolitan Istanbul to sewer systems indicating that chemical treatment is insufficient for discharging chemically pre‐treated dairy wastewater to a sewage system, which was actually the main objective of the study. The results showed that the wastewater composition greatly influences the maximum removal efficiencies and also the conditions for optimum coagulation. However, attention to such chemical treatment studies on dairy wastewater has started to accelerate within the last decade in various countries of the world, such as United Arabic Emirates and Scandinavian countries where the targets of applying chemical treatment varied. In Scandinavian countries, biodegradable coagulants have been applied to use the sludge arising from the system for livestock feeding, leading to reuse of sludge. In Arabic Emirates, chemically treated dairy effluents are utilised for irrigation purposes. These recent studies point out that application of chemical treatment to dairy wastewater with various coagulants lead to a variety of utilities apart from being a pre‐treatment alternative.