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Nickel-aluminum bronze (NAB) has been widely used in ship propellers. It is always subjected to local micro-plastic deformation in service environments. This paper aims to study the influence of plastic deformation on the mechanical strength and corrosion resistance of NAB in 3.5 Wt.% NaCl solution.

Scanning electron microscope and X-ray diffraction were used to analyze the microstructure of NAB alloy with different plastic deformations. Mechanical properties of the sample were measured by tensile experiment, and corrosion behavior was studied by electrochemical measurements and the long-term immersion corrosion test.

Results showed that the plastic deformation caused lattice distortion but did not change the microstructure of NAB alloy. Microhardness and yield strength of NAB were significantly improved with the increase of deformation. The lattice distortion accelerated the formation of corrosion product film, which made the deformed alloy show a more positive open-circuit potential and an increased Rp. However, during the long-term immersion corrosion, the corrosion resistance of NAB alloys deteriorated with the increase of plastic deformation. This is because larger plastic deformation brought about higher internal stress in corrosion product film, which resulted in the premature peeling of the film and the loss of its protective effect on the alloy substrate.

Tensile plastic deformations were found to cause a decline in the corrosion resistance of NAB. And the mechanism was clarified from the evolution of corrosion products during the corrosion process.

This study aims to investigate the influence mechanism of brazing and aging on the strengthening and corrosion behavior of novel multilayer sheets (AA4045/AA7072/AA3003M/AA4045).

Polarization curve tests, immersion experiments and transmission electron microscopy analysis were used to study the corrosion behavior and tensile properties of the sheets before and after brazing and aging.

The strength of the sheet is weakened after brazing due to brittle eutectic phases, and recovered after aging due to enhanced precipitation strengthening in the AA7072 interlayer. The core of nonbrazed sheets cannot be protected due to the significant galvanic coupling effect between the intermetallic particles and the substrate. Brazing and aging treatments promote the redissolved of second phased and limit corrosion along the eutectic region in the clad, allowing the core to be protected.

AA7xxx alloy was added to conventional brazed sheets to form a novel Al alloy composite sheet with AA4xxx/AA7xxx/AA3xxx structure. The strengthening and corrosion mechanism of the sheet was proposed. The added interlayer can sacrificially protect the core from corrosion and improves strength after aging treatment.

This paper aims to study the effect of chloride concentration on the properties of passive film formed on Q235 steel in simulated concrete pore solutions.

Mott–Schottky analysis and electrochemical impedance spectroscopy were used to study the passive film of Q235 steel in simulated concrete pore solution. X-ray photoelectron spectroscopy was used to analyze the composition of passive film on Q235 steel.

When the chloride concentration is below the chloride threshold value, open circuit potential (OCP) and Rct gradually increases and donor concentration (N_D) remains unchanged with the increasing immersion time. When the chloride concentration exceeds chloride threshold value, OCP and Rct decreases after a temporary increase and N_D increases. The linear region of the Mott–Schottky curve lost its linearity. The electrochemical process control step is changed from charge transfer control to oxygen diffusion control. As the chloride concentration increases, the FeO content in the passive film increases and the Fe₂O₃ content decreases. Chloride can destroy the outer layer of passive film and introduce impurities.

The effects of chloride and immersion time on the change process of passive films on Q235 steel in simulated concrete pore solution were studied using electrochemical methods. The mechanism of chloride destroying passive film was analyzed.

This paper aims to investigate the electrochemical corrosion behavior of a five-layer Al alloy composites (4343/4047/3003/4047/4343) with a thickness of 0.2 mm in NaCl solution.

Electrochemical impedance spectroscopy, polarization curve and morphology analyses were used to study the corrosion behavior of the Al alloy composites from cross-sectional and plane directions.

The corrosion resistance of the surface from the plane direction was higher than that from the cross sections. Si-enrich particles were observed in the outer 4047/4343 layer, and AlFeCuMnBi phases were identified in the core 3003 layer. The galvanic coupling between the Si-enrich particle and the Al matrix accelerated the dissolution Al matrix.

This work lays the experimental foundation for corrosion mechanism of the Al alloy composite plate.

The purpose of this paper is to clarify the effect of compressive stress on cavitation-erosion corrosion behavior of 304 stainless steel.

Compressive stresses of 60 MPa and 120 MPa were applied to 304 stainless steel through a self-designed loading device, and cavitation erosion-corrosion tests were performed using an ultrasonically vibratory apparatus. Scanning electron microscope and X-ray diffraction were used to analyze the microstructure evolution, and corrosion behavior was studied by electrochemical analysis.

The cavitation weight loss of 304 stainless steel decreased with the compressive stress. After cavitation corroded for 8 h, the weight loss for the specimen with 120 MPa compressive stress was 5.11 mg/cm², which was reduced by 56.7% from that of the specimen without loading stress (11.79 mg/cm²). The reason can be attributed to that compressive stress promoted the deformation-induced martensitic transformation during the cavitation process, which could not only provide a cushioning effect by absorbing cavitation impact energy but also improve the hardness of 304 stainless steel.

Compressive stress was found to restrain the cavitation damage on 304 stainless steel, and the corresponding mechanism was proposed.

This study aims to investigate the corrosion inhibitor effect of migrating corrosion inhibitor (MCI) on Q235 steel in high alkaline environment under cathodic polarization.

This study investigated the electrochemical characteristics of Q235 steel with and without MCI by polarization curve and electrochemical impedance spectroscopy. Besides, the surface composition of Q235 steel under different environments was analyzed by X-ray photoelectron spectroscopy. In addition, the migration characteristic of MCI and the adsorption behavior of MCI under cathodic polarization were studied using Raman spectroscopy.

Diethanolamine (DEA) and N, N-dimethylethanolamine (DMEA) can inhibit the increase of Fe(II) in the oxide film of Q235 steel under cathodic polarization. The adsorption stability of DMEA film was higher under cathodic polarization potential, showing a higher corrosion inhibition ability. The corrosion inhibition mechanism of DEA and DMEA under cathodic polarization potential was proposed.

The MCI has a broad application prospect in the repair of damaged reinforced concrete due to its unique migratory characteristics. The interaction between MCIs, rebar and concrete with different compositions has been studied, but the passivation behavior of the steel interface in the presence of both the migrating electric field and corrosion inhibitors has been neglected. And it was investigated in this paper.

The purpose of this paper is to prepare a multifunctional nanocomposite that is slow-release and resistant to seawater corrosion and biofouling corrosion and to explore the synergistic effect between the two corrosion inhibitors.

The morphology, structure and release properties of CAP@HNTs, BTA@HNTs and CAP/BTA@HNTs were investigated by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, specific surface area analysis and UV spectrophotometry. The corrosion resistance and antimicrobial properties were investigated by electrochemical measurements and bioinhibition rate tests, and the synergistic effect between the two corrosion inhibitors was explored by X-ray photoelectron spectroscopy.

The CAP/BTA@HNTs are responsive to acidic environments and have significantly improved antibacterial and corrosion resistance compared with CAP@HNTs and BTA@HNTs. CAP and BTA have a positive synergistic effect on anticorrosion and antifouling.

Two types of inhibitors, anticorrosion and antifouling, were loaded into the same nanocontainer to prepare a slow-releasable and multifunctional nanocomposite with higher resistance to seawater corrosion and biocorrosion and to explore the synergistic effect of CAP and BTA on corrosion resistance.

The purpose of this study is to reveal the effect of nano-Al₂O₃ particle addition on the nucleation/growth kinetics, microhardness, wear resistance and corrosion resistance of Co–P–xAl₂O₃ nanocomposite plating.

The kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating prepared by electroplating were investigated by electrochemical measurements, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Vickers microhardness measurement, SRV5 friction and wear tester and atomic force microscopy.

A 12 g/L nano-Al₂O₃ addition in the plating solution can transform the nucleation/growth kinetics of the plating from the 3D progressive model to the 3D instantaneous model. The microhardness of the plating increased with the increase of nano-Al₂O₃ content in plating. The wear resistance of the plating did not adhere strictly to Archard’s law. An even and denser corrosion product film was generated due to the finer grains, with a high corrosion resistance.

The effect of different nano-Al₂O₃ addition on the nucleation/growth kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating was investigated, and an anticorrosion mechanism of Co–P–xAl₂O₃ nanocomposite plating was proposed.

The purpose of this paper is to improve the corrosion resistance of stainless-steel bipolar plate by magnetron sputtering.

TiC/amorphous carbon composite film was deposited by magnetron sputter at four different temperature of 25°C, 200°C, 300°C and 400°C. The morphology, composition and structure of the film were characterized by scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. And its corrosion behavior was analyzed through electrochemical impedance spectroscopy, potentiodynamic and potentiostatic polarization tests.

A compact TiC/amorphous carbon film was prepared by magnetron sputtering on 316L stainless steel, and the particles of the film were refined with the increase in sputtering temperature. High temperature promoted the formation of TiC and C–C sp² hybrid carbon, but excessively high temperature caused the oxidation of Ti and a significant decrease in sp² hybrid carbon. The corrosion resistance of the film increased with the temperature, and the corrosion current density polarization at 0.86 V and 1.8 V for TiC/a–C film prepared at 400 °C is only 1.2% and 43.2% of stainless steel, respectively.

The corrosion resistance of amorphous carbon films was improved by the doping of Ti carbide, and the appropriate sputtering temperature was obtained.

The purpose of this study is to ensure the safe use of carbon fiber composite pressure vessels in the nuclear industry environment.

This study investigated the degradation behaviors of carbon fiber reinforced composite (CFRP) using the specific corrosive media HF solution, with a focus on the damage to the surface epoxy layer. The degradation behaviors of CFRP in HF solution were examined by electrochemical methods and surface characterization, using HCl, NaCl and NaF solution for comparison.

The results showed that the specimen in HF solution will have a value of |Z|_0.01 Hz one order of magnitude lower, a substantially lower contact angle, more breakage of the surface epoxy and the stronger O─H peak and weaker C─O─C peak in the Fourier transform infrared spectrum, indicating severe hydrolytic damage to the surface epoxy.

The work focuses on the degradation damage to CFRP surface epoxy by specific corrosive media HF.