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This study aims to control the oxidation resistance of Co-based deformed superalloys by adding trace elements Hf and Si.

The effects and mechanism of trace elements Hf and Si on the oxidation behavior of Co-Ni-Al-W-based forged superalloys were investigated by cyclic oxidation at 900°C.

The results show that the addition of trace elements Hf and Si does not affect the type of surface oxides of Co-Ni-based superalloys, and the oxidation layers of the alloys are TiO₂, spinel, Cr₂O₃, TaTiO₄, Al₂O₃ and TiN from outside to inside. However, the addition of elements can affect the activity of Cr and Ti elements; decrease the formation of TiO₂ and TaTiO₄ layers, which are harmful to the oxidation performance; and then improve the oxidation resistance of the alloy.

The relevant research results can not only optimize the microalloying element content of Co-Ni-Al-W-based superalloys, but also provide a new perspective for the composition optimization design of superalloys.

Due to the special service environment of superalloys, this paper aims to obtain effects of temperature and Ti addition on high temperature oxidation behavior of Co-Al-W-B alloys.

Isothermal oxidation experiment of Co-Al-W-based alloys were carried out at 800°C, 900°C and 1000°C for different times (3, 5, 10, 20, 50 and 100 h) referring to the method of HB5258-2000. Oxidation weight gain curves and oxidation products were detected.

The results showed that the average oxidation rates of Co-Al-W-B alloy at 800 °C and 900 °C were 0.489 g·m⁻²·h⁻¹ and 0.888 g·m⁻²·h⁻¹, respectively, which belonged to an antioxidant grade. However, the average oxidation rate at 1000 °C was 2.068 g m⁻²·h⁻¹, belonging to the secondary oxidation resistance class. In the alloy with Ti addition, dense Ti oxides film were formed at the early oxidation stage and then gradually diffused later, which can increase the oxidation resistance of the alloys to some extent. By analyzing the oxidation products of Co-Al-W-B alloy, it was found that a dense Al₂O₃ layer could be formed when the alloy was oxidized at 800°C. The continuous Al₂O₃ layer would prevent the oxygen from further spreading and make the alloy into the stable oxidation stage. However, only a non-dense Al₂O₃ layer were observed with 900°C oxidation.

It can provide references for the composition design, preparation process optimization and protective coating selection of the γ′ phase strengthened cobalt-base superalloys.

Alternating current (AC) corrosion is a type of corrosion that occurs in buried pipelines under AC stray current interference, which can increase the hydrogen embrittlement sensitivity of pipelines. However, rare research works have been conducted on the hydrogen permeability characteristics of pipeline steel under AC stray current interference. The purpose of this paper is to study hydrogen permeation behavior of X80 steel under AC stray current interference.

In this paper, the hydrogen permeation behavior of X80 steel under AC interference is studied by AC hydrogen charging experiment in a dual electrolytic cell. The relationship between hydrogen evolution rate and hydrogen permeation flux is studied using the gas collection method. The difference between AC hydrogen permeability and direct current (DC) hydrogen permeability is also discussed.

The anodic dissolution caused by AC corrosion promotes the chemical desorption reaction of the adsorbed hydrogen atoms on the surface, reducing the hydrogen atom absorption ratio by 70%. When the AC is smaller than 150░ A/m², the hydrogen permeation process is controlled by the hydrogen atom generation rate, and the hydrogen permeation flux increases with the increase in hydrogen atom generation rate. When the AC exceeds 400░ A/m², the hydrogen permeation process is controlled by the absorption ratio. The hydrogen permeation flux decreases with the decrease in the absorption ratio. Under AC interference, there is a maximum hydrogen permeation flux that linearly correlates to the H⁺ concentration in the solutions.

The high-strength steel is very sensitive to hydrogen embrittlement, and X80 steel has been widely used in oil and gas pipelines. To date, no research has been conducted on the hydrogen permeation behavior of pipeline steel under AC interference, and the hydrogen permeability characteristics of pipeline steel under AC interference are not clear. The research results of this paper are of great significance for ensuring the intrinsic safety of high-strength pipelines under AC stray current interference.

This study aims to improve the corrosion resistance of TA2-welded joints by superhydrophobic surface modification using micro-arc oxidation technology and low surface energy substance modification.

The microstructure and chemical state of the superhydrophobic film layer were analyzed using scanning electron microscopy, energy dispersive X-ray spectroscopy, three-dimensional morphology, X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transform infrared absorption spectroscopy. The influence of the superhydrophobic film layer on the corrosion resistance of TA2-welded joints was investigated using classical electrochemical testing methods.

The characterization results showed that the super hydrophobic TiO₂ ceramic membrane was successfully constructed on the surface of the TA2-welded joint, and the construction of the super hydrophobic film greatly improved the corrosion resistance of the TA2-welded joint.

The superhydrophobic TiO₂ ceramic membrane has excellent corrosion resistance. The micro nanostructure in the superhydrophobic film can intercept air to form an air layer to prevent the corrosion medium from contacting the surface, thus, improving the corrosion resistance of the sample.

The impact strength of solder joint under high strain rate was evaluated by board level test method. However, the impact shear test of single solder bump was more convenient and economical than the board level test method. With the miniaturization of solder joints, solder joints were more prone to failure under thermal shock and more attention has been paid to the impact reliability of solder joint. But Pb-free solder joints may be paid too much attention and Sn-Pb solder joints may be ignored.

In this study, thermal shock test between −55°C and 125°C was conducted on Sn-37Pb solder bumps in the BGA package to investigate microstructural evolution and growth mechanism of interfacial intermetallic compounds (IMCs) layer. The effects of thermal shock and ball diameter on the mechanical property and fracture behavior of Sn-37Pb solder bumps were discussed.

With the increase of ball size, the same change tendency of shear strength with thermal shock cycles. The shear strength of the solder bumps was the highest after reflow; with the increase of the number of thermal shocks, the shear strength of the solder bumps was decreased. But at the time of 2,000 cycles, the shear strength was increased to the initial strength. Minimum shear strength almost took place at 1,500 cycles in all solder bumps. The differences between maximum shear strength and minimum shear strength were 9.11 MPa and 16.83 MPa, 17.07 MPa and 15.59 MPa in φ0.3 mm and φ0.4 mm, φ0.5 mm and φ0.6 mm, respectively, differences were increased with increasing of ball size. With similar reflow profile, the thickness of IMC decreased as the diameter of the ball increased. The thickness of IMC was 2.42 µm and 2.17 µm, 1.63 µm and 1.77 µm with increasing of the ball size, respectively.

Pb-free solder was gradually used to replace traditional Sn-Pb solder and has been widely used in industry. Nevertheless, some products inevitably used a mixture of Sn-Pb and Pb-free solder to make the transition from Sn-Pb to Pb-free solder. Therefore, it was very important to understand the reliability of Sn-Pb solder joint and more further research works were also needed.

The purpose of this paper was to investigate the corrosion behaviour of API X65 pipeline steel in the simulated CO₂/oil/water emulsion using weight loss technique, potentiodynamic polarization technique and characterization of the corroded surface techniques.

The weight loss analysis, electrochemical study and surface investigation were carried out on API X65 pipeline steel that had been immersed in the CO₂/oil/water corrosive medium to understand the corrosion behaviour of gathering pipeline steel. The weight loss tests were carried out in a 3L autoclave, and effects of temperature, CO₂ partial pressure, water cut and flow velocity on the CO₂ corrosion rate of API X65 pipeline steel were studied. Electrochemical studies were carried out in a three-electrode electrochemical cell with the test temperature was 60°C, and the CO₂ partial pressure was 1 atm by recording open circuit potential/time and potentiodynamic polarization characteristics. The surface and cross-sectional morphologies of corrosion product scales were characterized using scanning electron microscopy. The phases of corrosion product scales were investigated using X-ray diffraction.

The results showed that water cut was the main controlling factor of API X65 steel corrosion under the conditions of CO₂/oil/water multiphase flow, and it had significant impact on corrosion morphology. In the case of higher water cut or pure water phase, general corrosion occurred on the steel surface. While water cut was below 70 per cent, corrosion morphology transformed into localized corrosion, crude oil decreased corrosion rate significantly and played a role of inhibitor. Crude oil hindered the corrosion scales from being dissolved by corrosive medium and changed dimension and accumulation pattern of the crystal grain, thickness and structure of the corrosion scales; thus, it influenced the corrosion rate. The primary corrosion product of API X65 steel was ferrous carbonate, which could act as a protective film at low water cut so that the corrosion rate can be reduced.

The results can be helpful in selecting the suitable corrosion inhibitors and targeted anti-corrosion measures for CO₂/oil/water corrosive environment.

This paper aims to provide a posture generation method of robot deposition paths based on intersection topology, which is helpful to contribute to improving the flexibility and deposition capability of the deposition system.

Via the geometry information and normal vector information of the stereolithography (STL) model, the intersecting edge information is generated and the topological relationship of the model is established. Through the removal of redundant points for the STL model and the sort of robot path points, the position information of robot path points is obtained. According to the geometric relationship between the normal vector information of the STL model and the robot deposition path points, combining with the robot posture representation method of roll-pitch-yaw angles, the posture information of path points is achieved. Then, the generation from CAD model of parts to robot paths for laser melting is realized, and the experimental verification is carried out.

For simple parts, the laser melting process can be completed without the posture information of deposition paths. However, in the melting process of a turbine blade, there are some accumulated burls on the sidewall. The posture generation method of robot deposition paths based on the intersection topology can solve this problem. The light spot of deposition points irradiates on the surface of the forming part, and the forming process can proceed smoothly.

As a motion platform in laser melting deposition (LMD), the application of the multi-joint robot can improve the flexibility and deposition capability of the deposition system, as well as promote the LMD application for individuation manufacturing, parts repair and green remanufacturing.

The posture is essential for robot deposition paths. This paper first proposes a posture generation method of deposition paths for LMD to improve the flexibility and deposition capability of LMD systems.

The article gives an introduction to the wine market in China and outlines its development. It goes on to identify the key issues which need to be addressed in order to enter the market successfully. These revolve, tactically, around effective mangement of the 4 P's, with distribution and promotion being the most problematic. It would appear that cultural differences and both formal and informal entry barriers point towards a more strategic relational approach if successful market entry is to be achieved. The implications for would‐be market entrants are discussed, as is the need for specific further research into market structure.

The purpose of this paper is to consider the role of accounting in the construction and maintenance of political hegemony during Mao’s People’s Commune movement in China between 1958 and 1966. Drawing on concepts of ideological power and intellectual diffusion in political and civil society from Gramsci’s theory of hegemony, it analyses the process by which accounting intellectuals established a set of socialist accounting practices to meet the political challenges of the People’s Commune.

Gramsci’s theory is adopted to examine how the accounting systems of People’s Commune acted as a mechanism that reflected Mao’s political ideas.

This paper demonstrates that the accounting system that emerged during these socio-political movements served the ideological purpose of reinforcing Mao’s political ideology and his hegemonic leadership. Accounting functioned within the spheres of both political and civil society to facilitate a national collective will, and to construct behaviours that satisfied the political requirements of the People’s Commune.

This paper will contribute to the accounting history in China from 1958 to 1966.