Four-point method in evaluating the corrosion rate of secondary circuit structural materials in nuclear power plant

Abstract

Purpose

The purpose of this paper is to optimize a suitable electrochemical method in evaluating the corrosion rate of structural materials of 20# carbon steel, P280GH carbon steel, 17-4PH stainless steel, 304 stainless steel and Alloy 690TT in high-temperature and high-pressure (HTHP) water of pressurized water reactor secondary circuit system.

Design/methodology/approach

Weight-loss method has been used to obtain the corrosion rate value of each structural material in simulated HTHP water. Besides, linear polarization method and weak polarization curve-based three-point method and four-point method have been compared in obtaining a sound corrosion rate value from the potentiodynamic polarization curve. Scanning electron microscopy (SEM) and atomic force microscope have been used to characterize the microstructure and corrosion morphology of each structural material.

Findings

Although there is deviation in gaining the corrosion rate value compared to weight-loss test, the weak polarization curve-based four-point method has been found to be a suitable electrochemical method in gaining corrosion rate value of structural materials in HTHP waters.

Originality/value

This paper proposes a suitable and reliable electrochemical method in gaining the corrosion rate value of structural materials in HTHP waters. The proposed weak polarization curve-based four-point method provides a timesaving and high-efficient way in corrosion rate evaluation of secondary circuit structural materials and thus has a potential application in nuclear power plants.

Citation

Ji, Y., Hao, L., Wang, J., Han, E.-H. and Ke, W. (2024), "Four-point method in evaluating the corrosion rate of secondary circuit structural materials in nuclear power plant", Anti-Corrosion Methods and Materials, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/ACMM-09-2024-3091