Corrosion inhibition performance of expired amlodipine on cupronickel alloy in a neutral chloride environment: electrochemical and surface analysis

Abstract

Purpose

The corrosion of cupronickel and copper alloys in marine and chloride environments presents significant challenges in the chemical and petrochemical industries. This paper aims to investigate the corrosion inhibition of cupronickel alloy (Cu-10Ni) in a sodium chloride medium using expired amlodipine as a corrosion inhibitor. The use of this drug in its expired form could reduce the costs of corrosion and help mitigate the accumulation of pharmaceutical waste.

Design/methodology/approach

The inhibitory action was evaluated using a weight loss method, potentiodynamic polarization, electrochemical impedance spectroscopy measurements, scanning electron microscopy (SEM) and atomic force microscopy (AFM). The effect of temperature on the inhibition performance was also studied.

Findings

The results of these experiments demonstrated that the drug amlodipine effectively inhibited the corrosion of cupronickel alloy in chloride solutions. The corrosion rate of cupronickel was found to decrease with increasing inhibitor concentration and to increase with rising temperature. A maximum inhibition efficiency of 91.92 was achieved with an inhibitor concentration of 0.025 g/L at 298 K. Adsorption of the inhibitor followed the Langmuir adsorption isotherm. Polarization studies indicated that the expired drug acted as a mixed inhibitor. SEM and AFM analyses confirmed that the surface morphology of cupronickel specimens was significantly improved in the presence of the inhibitor.

Practical implications

Amlodipine can be conveniently used to mitigate problems with the corrosion of copper alloys in chloride environments.

Originality/value

Amlodipine is evaluated as a novel and effective corrosion inhibitor for cupronickel alloy in neutral chloride environments.

Citation

Kherraf, S., Foudia, M., Sobhi, N.E.H., Djetoui, Z. and Medjram, M.S. (2025), "Corrosion inhibition performance of expired amlodipine on cupronickel alloy in a neutral chloride environment: electrochemical and surface analysis", Anti-Corrosion Methods and Materials, Vol. 72 No. 1, pp. 48-60. https://doi.org/10.1108/ACMM-07-2024-3060